Catalytic synthesis of nanosized feathery carbon structures via the carbide cycle mechanism

I. V. Mishakov, R. A. Buyanov, V. I. Zaikovskii, I. A. Strel'tsov, A. A. Vedyagin

Research output: Contribution to journalArticle

16 Citations (Scopus)

Abstract

The morphology of carbon nanostructures obtained by 1,2-dichloroethane decomposition on the 90% Ni/Al2O3 catalyst under different reaction conditions was studied by high-resolution transmission electron microscopy. A new carbon product was discovered, which received the name of feathery carbon. The product has an extremely loose disordered structure consisting of separate fragments of a graphite-like phase. The structural disordering is assumed to be caused by the variation of chlorohydrocarbon decomposition conditions on the frontal face of the metal particle. This changes the character of carbon atom diffusion from the frontal face to the backside face of the nickel particles and finally results in a feathery morphology of the carbon phase. The specific surface area of feathery carbon is 300-400 m 2/g.

Original languageEnglish
Pages (from-to)868-872
Number of pages5
JournalKinetics and Catalysis
Volume49
Issue number6
DOIs
Publication statusPublished - Nov 2008
Externally publishedYes

Fingerprint

Carbides
Carbon
Synthesis
Cycle
Face
Decomposition
Decompose
Graphite
Nickel
Transmission Electron Microscopy
High resolution transmission electron microscopy
Surface area
Nanostructures
Catalyst
Specific surface area
Fragment
High Resolution
Metals
Atoms
Catalysts

ASJC Scopus subject areas

  • Catalysis
  • Chemistry(all)
  • Modelling and Simulation
  • Computer Science Applications

Cite this

Catalytic synthesis of nanosized feathery carbon structures via the carbide cycle mechanism. / Mishakov, I. V.; Buyanov, R. A.; Zaikovskii, V. I.; Strel'tsov, I. A.; Vedyagin, A. A.

In: Kinetics and Catalysis, Vol. 49, No. 6, 11.2008, p. 868-872.

Research output: Contribution to journalArticle

Mishakov, I. V. ; Buyanov, R. A. ; Zaikovskii, V. I. ; Strel'tsov, I. A. ; Vedyagin, A. A. / Catalytic synthesis of nanosized feathery carbon structures via the carbide cycle mechanism. In: Kinetics and Catalysis. 2008 ; Vol. 49, No. 6. pp. 868-872.
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