Abstract
Catalytic activity and surface properties of the mixed catalysts for the dimethyl ether synthesis from CO and H2 are presented in paper. Catalytic experiments were carried out in flow reactor at 3 MPa and temperature interval 200-260 °C. As a catalyst for methanol synthesis it was used CuO/ZnO/Al2O3 sample and as catalyst for hydration of methanol was used zeolite. It was established that mixture of the composition 13 % CuO/27 % ZnO/60 % Al2O3 and zeolite HZSM-5 (silicate module - ratio SiO2/Al2O3 = 30) has high activity and show the yield at about 40 %. It is proposed influence of the catalysts nature on the catalytic properties.
| Original language | English |
|---|---|
| Title of host publication | Proceedings - 2012 7th International Forum on Strategic Technology, IFOST 2012 |
| DOIs | |
| Publication status | Published - 1 Dec 2012 |
| Event | 2012 7th International Forum on Strategic Technology, IFOST 2012 - Tomsk, Russian Federation Duration: 18 Sep 2012 → 21 Sep 2012 |
Conference
| Conference | 2012 7th International Forum on Strategic Technology, IFOST 2012 |
|---|---|
| Country | Russian Federation |
| City | Tomsk |
| Period | 18.9.12 → 21.9.12 |
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Keywords
- dimethil ether
- methanol
- mixed catalysts
- synthesis gas
- zeolite
ASJC Scopus subject areas
- Management of Technology and Innovation
Cite this
Catalytic activity of the dehydration catalysts for dimethyl ether synthesis. / Musich, P. G.; Kurzina, I. A.; Vosmerikova, L. N.; Kurina, L. N.; Vosmerikov, A. V.
Proceedings - 2012 7th International Forum on Strategic Technology, IFOST 2012. 2012. 6357518.Research output: Chapter in Book/Report/Conference proceeding › Conference contribution
}
TY - GEN
T1 - Catalytic activity of the dehydration catalysts for dimethyl ether synthesis
AU - Musich, P. G.
AU - Kurzina, I. A.
AU - Vosmerikova, L. N.
AU - Kurina, L. N.
AU - Vosmerikov, A. V.
PY - 2012/12/1
Y1 - 2012/12/1
N2 - Catalytic activity and surface properties of the mixed catalysts for the dimethyl ether synthesis from CO and H2 are presented in paper. Catalytic experiments were carried out in flow reactor at 3 MPa and temperature interval 200-260 °C. As a catalyst for methanol synthesis it was used CuO/ZnO/Al2O3 sample and as catalyst for hydration of methanol was used zeolite. It was established that mixture of the composition 13 % CuO/27 % ZnO/60 % Al2O3 and zeolite HZSM-5 (silicate module - ratio SiO2/Al2O3 = 30) has high activity and show the yield at about 40 %. It is proposed influence of the catalysts nature on the catalytic properties.
AB - Catalytic activity and surface properties of the mixed catalysts for the dimethyl ether synthesis from CO and H2 are presented in paper. Catalytic experiments were carried out in flow reactor at 3 MPa and temperature interval 200-260 °C. As a catalyst for methanol synthesis it was used CuO/ZnO/Al2O3 sample and as catalyst for hydration of methanol was used zeolite. It was established that mixture of the composition 13 % CuO/27 % ZnO/60 % Al2O3 and zeolite HZSM-5 (silicate module - ratio SiO2/Al2O3 = 30) has high activity and show the yield at about 40 %. It is proposed influence of the catalysts nature on the catalytic properties.
KW - dimethil ether
KW - methanol
KW - mixed catalysts
KW - synthesis gas
KW - zeolite
UR - http://www.scopus.com/inward/record.url?scp=84871825807&partnerID=8YFLogxK
UR - http://www.scopus.com/inward/citedby.url?scp=84871825807&partnerID=8YFLogxK
U2 - 10.1109/IFOST.2012.6357518
DO - 10.1109/IFOST.2012.6357518
M3 - Conference contribution
AN - SCOPUS:84871825807
SN - 9781467317702
BT - Proceedings - 2012 7th International Forum on Strategic Technology, IFOST 2012
ER -