Carrying out thermodynamic calculations and definition of the main reactions of decomposition of vapours of ethyl alcohol

A. I. Sechin, O. S. Kyrmakova, T. A. Ivanova

Research output: Chapter in Book/Report/Conference proceedingConference contribution

Abstract

Thermodynamic opportunities of course of chemical reactions of decomposition of the vapors of ethyl alcohol necessary at development of devices where these reactions will take place are considered. The entalpiyny method of calculation of constants of balance of probable chemical reactions is given in the Excel editor. Independent reactions of process of oxidation are defined. By result of thermodynamic calculation of each reaction schedules of dependence of a constant of balance on environment temperature from which follows are constructed that one reactions proceed until the end of aside formation of the final products, and others are improbable or impossible. The analysis of the received results shows that reactions of oxidation will successfully proceed in the established directions, and for an intensification of process of decomposition it is necessary to provide a supply of some energy which quantity will be sufficient for oxidation of vapors of ethyl alcohol. Results of calculations showed good convergence with programs of thermodynamic calculations like "Aster - 4" and "TERRA".

Original languageEnglish
Title of host publicationIOP Conference Series: Materials Science and Engineering
PublisherInstitute of Physics Publishing
Volume81
Edition1
DOIs
Publication statusPublished - 23 Apr 2015
EventInternational Scientific Conference on Radiation-Thermal Effects and Processes in Inorganic Materials, RTEP 2014 - Tomsk, Russian Federation
Duration: 3 Nov 20148 Nov 2014

Other

OtherInternational Scientific Conference on Radiation-Thermal Effects and Processes in Inorganic Materials, RTEP 2014
CountryRussian Federation
CityTomsk
Period3.11.148.11.14

Fingerprint

Ethanol
Vapors
Thermodynamics
Decomposition
Oxidation
Chemical reactions
Temperature

ASJC Scopus subject areas

  • Engineering(all)
  • Materials Science(all)

Cite this

Sechin, A. I., Kyrmakova, O. S., & Ivanova, T. A. (2015). Carrying out thermodynamic calculations and definition of the main reactions of decomposition of vapours of ethyl alcohol. In IOP Conference Series: Materials Science and Engineering (1 ed., Vol. 81). [012109] Institute of Physics Publishing. https://doi.org/10.1088/1757-899X/81/1/012109

Carrying out thermodynamic calculations and definition of the main reactions of decomposition of vapours of ethyl alcohol. / Sechin, A. I.; Kyrmakova, O. S.; Ivanova, T. A.

IOP Conference Series: Materials Science and Engineering. Vol. 81 1. ed. Institute of Physics Publishing, 2015. 012109.

Research output: Chapter in Book/Report/Conference proceedingConference contribution

Sechin, AI, Kyrmakova, OS & Ivanova, TA 2015, Carrying out thermodynamic calculations and definition of the main reactions of decomposition of vapours of ethyl alcohol. in IOP Conference Series: Materials Science and Engineering. 1 edn, vol. 81, 012109, Institute of Physics Publishing, International Scientific Conference on Radiation-Thermal Effects and Processes in Inorganic Materials, RTEP 2014, Tomsk, Russian Federation, 3.11.14. https://doi.org/10.1088/1757-899X/81/1/012109
Sechin AI, Kyrmakova OS, Ivanova TA. Carrying out thermodynamic calculations and definition of the main reactions of decomposition of vapours of ethyl alcohol. In IOP Conference Series: Materials Science and Engineering. 1 ed. Vol. 81. Institute of Physics Publishing. 2015. 012109 https://doi.org/10.1088/1757-899X/81/1/012109
Sechin, A. I. ; Kyrmakova, O. S. ; Ivanova, T. A. / Carrying out thermodynamic calculations and definition of the main reactions of decomposition of vapours of ethyl alcohol. IOP Conference Series: Materials Science and Engineering. Vol. 81 1. ed. Institute of Physics Publishing, 2015.
@inproceedings{011dc087fcff4c7aa45ed25fbb9bc232,
title = "Carrying out thermodynamic calculations and definition of the main reactions of decomposition of vapours of ethyl alcohol",
abstract = "Thermodynamic opportunities of course of chemical reactions of decomposition of the vapors of ethyl alcohol necessary at development of devices where these reactions will take place are considered. The entalpiyny method of calculation of constants of balance of probable chemical reactions is given in the Excel editor. Independent reactions of process of oxidation are defined. By result of thermodynamic calculation of each reaction schedules of dependence of a constant of balance on environment temperature from which follows are constructed that one reactions proceed until the end of aside formation of the final products, and others are improbable or impossible. The analysis of the received results shows that reactions of oxidation will successfully proceed in the established directions, and for an intensification of process of decomposition it is necessary to provide a supply of some energy which quantity will be sufficient for oxidation of vapors of ethyl alcohol. Results of calculations showed good convergence with programs of thermodynamic calculations like {"}Aster - 4{"} and {"}TERRA{"}.",
author = "Sechin, {A. I.} and Kyrmakova, {O. S.} and Ivanova, {T. A.}",
year = "2015",
month = "4",
day = "23",
doi = "10.1088/1757-899X/81/1/012109",
language = "English",
volume = "81",
booktitle = "IOP Conference Series: Materials Science and Engineering",
publisher = "Institute of Physics Publishing",
edition = "1",

}

TY - GEN

T1 - Carrying out thermodynamic calculations and definition of the main reactions of decomposition of vapours of ethyl alcohol

AU - Sechin, A. I.

AU - Kyrmakova, O. S.

AU - Ivanova, T. A.

PY - 2015/4/23

Y1 - 2015/4/23

N2 - Thermodynamic opportunities of course of chemical reactions of decomposition of the vapors of ethyl alcohol necessary at development of devices where these reactions will take place are considered. The entalpiyny method of calculation of constants of balance of probable chemical reactions is given in the Excel editor. Independent reactions of process of oxidation are defined. By result of thermodynamic calculation of each reaction schedules of dependence of a constant of balance on environment temperature from which follows are constructed that one reactions proceed until the end of aside formation of the final products, and others are improbable or impossible. The analysis of the received results shows that reactions of oxidation will successfully proceed in the established directions, and for an intensification of process of decomposition it is necessary to provide a supply of some energy which quantity will be sufficient for oxidation of vapors of ethyl alcohol. Results of calculations showed good convergence with programs of thermodynamic calculations like "Aster - 4" and "TERRA".

AB - Thermodynamic opportunities of course of chemical reactions of decomposition of the vapors of ethyl alcohol necessary at development of devices where these reactions will take place are considered. The entalpiyny method of calculation of constants of balance of probable chemical reactions is given in the Excel editor. Independent reactions of process of oxidation are defined. By result of thermodynamic calculation of each reaction schedules of dependence of a constant of balance on environment temperature from which follows are constructed that one reactions proceed until the end of aside formation of the final products, and others are improbable or impossible. The analysis of the received results shows that reactions of oxidation will successfully proceed in the established directions, and for an intensification of process of decomposition it is necessary to provide a supply of some energy which quantity will be sufficient for oxidation of vapors of ethyl alcohol. Results of calculations showed good convergence with programs of thermodynamic calculations like "Aster - 4" and "TERRA".

UR - http://www.scopus.com/inward/record.url?scp=84930461954&partnerID=8YFLogxK

UR - http://www.scopus.com/inward/citedby.url?scp=84930461954&partnerID=8YFLogxK

U2 - 10.1088/1757-899X/81/1/012109

DO - 10.1088/1757-899X/81/1/012109

M3 - Conference contribution

VL - 81

BT - IOP Conference Series: Materials Science and Engineering

PB - Institute of Physics Publishing

ER -