Calculation of the H2 18O rotational energy levels for the first hexad of interacting vibrational states

O. N. Ulenikov, A. S. Zhilyakov

Research output: Contribution to journalArticle

3 Citations (Scopus)

Abstract

The experimental rotational energy levels of six vibrational states, (021)-(101)-(120)-(200)-(002)-(040) (Canad. J. Phys., 64, 746-761 (1986)), of the H2 18O molecule have been fitted for determining the rotational, centrifugal, and resonance parameters. To correctly reproduce the initial experimental data, the effective vibration-rotation Hamiltonian has been improved. The parameters obtained from the fitting reproduce the initial experimental data with an average accuracy better than 0.01 cm-1.

Original languageEnglish
Pages (from-to)1-9
Number of pages9
JournalJournal of Molecular Spectroscopy
Volume133
Issue number1
DOIs
Publication statusPublished - 1989

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Hamiltonians
vibrational states
Electron energy levels
energy levels
Molecules
vibration
molecules

ASJC Scopus subject areas

  • Physical and Theoretical Chemistry
  • Spectroscopy
  • Atomic and Molecular Physics, and Optics

Cite this

Calculation of the H2 18O rotational energy levels for the first hexad of interacting vibrational states. / Ulenikov, O. N.; Zhilyakov, A. S.

In: Journal of Molecular Spectroscopy, Vol. 133, No. 1, 1989, p. 1-9.

Research output: Contribution to journalArticle

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