Calculation of the dependence of the centrifugal constants of the molecule H2O on the quantum number v2 on the basis of the Morse oscillator

Abstract

An explanation is given in this paper for the anomalous dependence of the centrifugal distortion in flexible molecules of the type H₂O on the "bending" quantum number v₂ on the basis of the Morse oscillator. A computation of the dependence of the rapidly varying rotational, quartic, sextic constants of the molecule H₂O on v₂ describes the experimental behavior of these constants well.

Original language	English
Pages (from-to)	762-765
Number of pages	4
Journal	Soviet Physics Journal
Volume	25
Issue number	8
DOIs	https://doi.org/10.1007/BF00895258
Publication status	Published - Aug 1982

ASJC Scopus subject areas

Physics and Astronomy(all)

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10.1007/BF00895258

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title = "Calculation of the dependence of the centrifugal constants of the molecule H2O on the quantum number v2 on the basis of the Morse oscillator",

abstract = "An explanation is given in this paper for the anomalous dependence of the centrifugal distortion in flexible molecules of the type H2O on the {"}bending{"} quantum number v2 on the basis of the Morse oscillator. A computation of the dependence of the rapidly varying rotational, quartic, sextic constants of the molecule H2O on v2 describes the experimental behavior of these constants well.",

author = "Starikov, {V. I.} and Tyuterev, {Vl G.}",

year = "1982",

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N2 - An explanation is given in this paper for the anomalous dependence of the centrifugal distortion in flexible molecules of the type H2O on the "bending" quantum number v2 on the basis of the Morse oscillator. A computation of the dependence of the rapidly varying rotational, quartic, sextic constants of the molecule H2O on v2 describes the experimental behavior of these constants well.

AB - An explanation is given in this paper for the anomalous dependence of the centrifugal distortion in flexible molecules of the type H2O on the "bending" quantum number v2 on the basis of the Morse oscillator. A computation of the dependence of the rapidly varying rotational, quartic, sextic constants of the molecule H2O on v2 describes the experimental behavior of these constants well.

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Calculation of the dependence of the centrifugal constants of the molecule H₂O on the quantum number v₂ on the basis of the Morse oscillator

Abstract

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