Calculation of the dependence of the centrifugal constants of the molecule H2O on the quantum number v2 on the basis of the Morse oscillator

V. I. Starikov, Vl G. Tyuterev

    Research output: Contribution to journalArticle

    Abstract

    An explanation is given in this paper for the anomalous dependence of the centrifugal distortion in flexible molecules of the type H2O on the "bending" quantum number v2 on the basis of the Morse oscillator. A computation of the dependence of the rapidly varying rotational, quartic, sextic constants of the molecule H2O on v2 describes the experimental behavior of these constants well.

    Original languageEnglish
    Pages (from-to)762-765
    Number of pages4
    JournalSoviet Physics Journal
    Volume25
    Issue number8
    DOIs
    Publication statusPublished - Aug 1982

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    quantum numbers
    oscillators
    molecules

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    Calculation of the dependence of the centrifugal constants of the molecule H2O on the quantum number v2 on the basis of the Morse oscillator. / Starikov, V. I.; Tyuterev, Vl G.

    In: Soviet Physics Journal, Vol. 25, No. 8, 08.1982, p. 762-765.

    Research output: Contribution to journalArticle

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