Calculation of the dependence of the centrifugal constants of the molecule H₂O on the quantum number v₂ on the basis of the Morse oscillator

V. I. Starikov, Vl G. Tyuterev

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Abstract

An explanation is given in this paper for the anomalous dependence of the centrifugal distortion in flexible molecules of the type H₂O on the "bending" quantum number v₂ on the basis of the Morse oscillator. A computation of the dependence of the rapidly varying rotational, quartic, sextic constants of the molecule H₂O on v₂ describes the experimental behavior of these constants well.

Original language	English
Pages (from-to)	762-765
Number of pages	4
Journal	Soviet Physics Journal
Volume	25
Issue number	8
DOIs	https://doi.org/10.1007/BF00895258
Publication status	Published - Aug 1982

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ASJC Scopus subject areas

Physics and Astronomy(all)

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Starikov, V. I., & Tyuterev, V. G. (1982). Calculation of the dependence of the centrifugal constants of the molecule H₂O on the quantum number v₂ on the basis of the Morse oscillator. Soviet Physics Journal, 25(8), 762-765. https://doi.org/10.1007/BF00895258

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Access to Document

10.1007/BF00895258