Bulk Ring-Opening Polymerization of ε-Caprolactone by Zeolitic Imidazolate Framework

Farah Naz, Fatima Mumtaz, Somboon Chaemchuen, Francis Verpoort

Research output: Contribution to journalArticle

Abstract

Abstract: In this work, for the first time, zeolitic imidazolate frameworks (ZIFs = ZIF-8, ZIF-67, and Zn/Co-ZIF), obtained via spray drying, were used as heterogeneous catalysts for the ring opening polymerization of ε-Caprolactone without any co-catalyst or initiator. The catalytic activity of the spray dried ZIFs series varies in the order of Zn/Co-ZIF < ZIF-67 < ZIF-8. It was found that the catalytic activities of ZIFs series correlate with the defects present in their structure. Among active sites of ZIFs, only the acid sites derived from structural defects are supposed to catalyse the polymerization reaction. Under optimal reaction conditions, ZIF-8 shows a superior catalytic activity compared to ZIF-67 or Zn/Co-ZIF and leads to the formation of higher molecular weight linear polycaprolactone. The recyclability test confirmed that the catalyst could be reused and no significant loss of catalytic activity was found after three uses. Graphical Abstract: [Figure not available: see fulltext.].

Original languageEnglish
Pages (from-to)2132-2141
Number of pages10
JournalCatalysis Letters
Volume149
Issue number8
DOIs
Publication statusPublished - 1 Aug 2019

Fingerprint

Ring opening polymerization
Catalyst activity
Catalysts
Initiators (chemical)
Polycaprolactone
Spray drying
Defects
Molecular weight
Polymerization
Acids
caprolactone

Keywords

  • Biodegradable polycaprolactone
  • Heterogeneous catalyst
  • Metal–organic frameworks
  • Ring-opening polymerization
  • Zeolitic imidazole frameworks

ASJC Scopus subject areas

  • Catalysis
  • Chemistry(all)

Cite this

Bulk Ring-Opening Polymerization of ε-Caprolactone by Zeolitic Imidazolate Framework. / Naz, Farah; Mumtaz, Fatima; Chaemchuen, Somboon; Verpoort, Francis.

In: Catalysis Letters, Vol. 149, No. 8, 01.08.2019, p. 2132-2141.

Research output: Contribution to journalArticle

Naz, Farah ; Mumtaz, Fatima ; Chaemchuen, Somboon ; Verpoort, Francis. / Bulk Ring-Opening Polymerization of ε-Caprolactone by Zeolitic Imidazolate Framework. In: Catalysis Letters. 2019 ; Vol. 149, No. 8. pp. 2132-2141.
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