Abstract
RbCl and CsCl react with BrF3 yielding the corresponding decafluoridotribromates(iii), MBr3F10 (M = Rb, Cs), which were structurally characterized for the first time. The Br3F10 - anion is surprisingly not linear but contains a μ3-bridging fluorine atom and seems to be the first example of μ3-F bridging of Br atoms. The compounds are highly reactive and cannot be handled in glassware. As for the tetrafluoridobromates themselves, they are powerful oxidizers and thus suitable for the dry-chemical recycling of precious metals and additionally feature a significantly higher BrF3 content.
| Original language | English |
|---|---|
| Pages (from-to) | 12040-12043 |
| Number of pages | 4 |
| Journal | Chemical Communications |
| Volume | 52 |
| Issue number | 81 |
| DOIs | |
| Publication status | Published - 2016 |
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ASJC Scopus subject areas
- Catalysis
- Electronic, Optical and Magnetic Materials
- Ceramics and Composites
- Chemistry(all)
- Surfaces, Coatings and Films
- Metals and Alloys
- Materials Chemistry
Cite this
Br2F7- and Br3F10-: peculiar anions showing mu(2)- and mu(3)-bridging F-atoms : Peculiar anions showing μ2- and μ3-bridging F-atoms. / Ivlev, S. I.; Karttunen, A. J.; Ostvald, R. V.; Kraus, F.
In: Chemical Communications, Vol. 52, No. 81, 2016, p. 12040-12043.Research output: Contribution to journal › Article
}
TY - JOUR
T1 - Br2F7- and Br3F10-: peculiar anions showing mu(2)- and mu(3)-bridging F-atoms
T2 - Peculiar anions showing μ2- and μ3-bridging F-atoms
AU - Ivlev, S. I.
AU - Karttunen, A. J.
AU - Ostvald, R. V.
AU - Kraus, F.
PY - 2016
Y1 - 2016
N2 - RbCl and CsCl react with BrF3 yielding the corresponding decafluoridotribromates(iii), MBr3F10 (M = Rb, Cs), which were structurally characterized for the first time. The Br3F10 - anion is surprisingly not linear but contains a μ3-bridging fluorine atom and seems to be the first example of μ3-F bridging of Br atoms. The compounds are highly reactive and cannot be handled in glassware. As for the tetrafluoridobromates themselves, they are powerful oxidizers and thus suitable for the dry-chemical recycling of precious metals and additionally feature a significantly higher BrF3 content.
AB - RbCl and CsCl react with BrF3 yielding the corresponding decafluoridotribromates(iii), MBr3F10 (M = Rb, Cs), which were structurally characterized for the first time. The Br3F10 - anion is surprisingly not linear but contains a μ3-bridging fluorine atom and seems to be the first example of μ3-F bridging of Br atoms. The compounds are highly reactive and cannot be handled in glassware. As for the tetrafluoridobromates themselves, they are powerful oxidizers and thus suitable for the dry-chemical recycling of precious metals and additionally feature a significantly higher BrF3 content.
UR - http://www.scopus.com/inward/record.url?scp=84990060971&partnerID=8YFLogxK
UR - http://www.scopus.com/inward/citedby.url?scp=84990060971&partnerID=8YFLogxK
U2 - 10.1039/c6cc06761a
DO - 10.1039/c6cc06761a
M3 - Article
VL - 52
SP - 12040
EP - 12043
JO - Chemical Communications
JF - Chemical Communications
SN - 1359-7345
IS - 81
ER -