Abstract
The broadening coefficients γ of absorption lines of the v 2 band of H2S molecules due to the pressure of molecular gases H2S (self-broadening), H2O, N2, O 2, H2, D2, and CO2 have been calculated by the semiclassical methods. A satisfactory agreement with the experimental data available for some lines has been achieved. In all cases, the parameters of an analytical model allowing the reconstruction of the calculated and experimental values of γ have been determined. For the case of line self-broadening, the calculation has been performed for several temperatures in the range 296 K ≤ T ≤ 1300 K and the parameters determining the temperature dependence of γ have been obtained.
| Original language | English |
|---|---|
| Pages (from-to) | 523-531 |
| Number of pages | 9 |
| Journal | Optics and Spectroscopy (English translation of Optika i Spektroskopiya) |
| Volume | 101 |
| Issue number | 4 |
| DOIs | |
| Publication status | Published - 1 Oct 2006 |
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ASJC Scopus subject areas
- Electronic, Optical and Magnetic Materials
- Atomic and Molecular Physics, and Optics
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Broadening of absorption lines of the v2 band of the H 2S molecule by the pressure of atmospheric gases. / Starikov, V. I.; Protasevich, A. E.
In: Optics and Spectroscopy (English translation of Optika i Spektroskopiya), Vol. 101, No. 4, 01.10.2006, p. 523-531.Research output: Contribution to journal › Article
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TY - JOUR
T1 - Broadening of absorption lines of the v2 band of the H 2S molecule by the pressure of atmospheric gases
AU - Starikov, V. I.
AU - Protasevich, A. E.
PY - 2006/10/1
Y1 - 2006/10/1
N2 - The broadening coefficients γ of absorption lines of the v 2 band of H2S molecules due to the pressure of molecular gases H2S (self-broadening), H2O, N2, O 2, H2, D2, and CO2 have been calculated by the semiclassical methods. A satisfactory agreement with the experimental data available for some lines has been achieved. In all cases, the parameters of an analytical model allowing the reconstruction of the calculated and experimental values of γ have been determined. For the case of line self-broadening, the calculation has been performed for several temperatures in the range 296 K ≤ T ≤ 1300 K and the parameters determining the temperature dependence of γ have been obtained.
AB - The broadening coefficients γ of absorption lines of the v 2 band of H2S molecules due to the pressure of molecular gases H2S (self-broadening), H2O, N2, O 2, H2, D2, and CO2 have been calculated by the semiclassical methods. A satisfactory agreement with the experimental data available for some lines has been achieved. In all cases, the parameters of an analytical model allowing the reconstruction of the calculated and experimental values of γ have been determined. For the case of line self-broadening, the calculation has been performed for several temperatures in the range 296 K ≤ T ≤ 1300 K and the parameters determining the temperature dependence of γ have been obtained.
UR - http://www.scopus.com/inward/record.url?scp=33750330691&partnerID=8YFLogxK
UR - http://www.scopus.com/inward/citedby.url?scp=33750330691&partnerID=8YFLogxK
U2 - 10.1134/S0030400X06100043
DO - 10.1134/S0030400X06100043
M3 - Article
AN - SCOPUS:33750330691
VL - 101
SP - 523
EP - 531
JO - Optics and Spectroscopy (English translation of Optika i Spektroskopiya)
JF - Optics and Spectroscopy (English translation of Optika i Spektroskopiya)
SN - 0030-400X
IS - 4
ER -