Abstract
Two binuclear iron(III) phthalocyanine-(μ-oxodimer) complexes were tested in catalytic oxygenation reactions of several aromatic hydrocarbons using iodosylbenzene (PhIO)n or oligomeric iodosylbenzene sulfate [(PhIO)3SO3]n as the oxidants. Results of this study demonstrate that [(PhIO)3SO3]n is the most reactive oxygenating reagent that can be used as a safe and convenient alternative to the thermally unstable and potentially explosive iodosylbenzene. The pyridine-containing binuclear μ-oxobis-{iron(III)-pyridino[3,4]-9(10), 16(17),23(24)-tri-tertbutyltribenzoporphyrazine} is significantly more active as compared to the traditional μ-oxobis[iron-(III)-2,9(10),16(17),23(24)-tetra- tert-butylphthalocyanine].
| Original language | English |
|---|---|
| Pages (from-to) | 3168-3174 |
| Number of pages | 7 |
| Journal | Advanced Synthesis and Catalysis |
| Volume | 351 |
| Issue number | 18 |
| DOIs | |
| Publication status | Published - Dec 2009 |
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Keywords
- Iodine
- Iodosylbenzene
- Iodosylbenzene sulfate
- Iron phthalocyanine μ-oxodimer
- Oxygenation
ASJC Scopus subject areas
- Catalysis
- Organic Chemistry
Cite this
Binuclear iron(III) phthalocyanine(μ-oxodimer)-catalyzed oxygenation of aromatic hydrocarbons with iodosylbenzene sulfate and iodosylbenzene as the oxidants. / Neu, Heather M.; Yusubov, Mekhman S.; Zhdankin, Viktor Vladimirovich; Nemykin, Victor N.
In: Advanced Synthesis and Catalysis, Vol. 351, No. 18, 12.2009, p. 3168-3174.Research output: Contribution to journal › Article
}
TY - JOUR
T1 - Binuclear iron(III) phthalocyanine(μ-oxodimer)-catalyzed oxygenation of aromatic hydrocarbons with iodosylbenzene sulfate and iodosylbenzene as the oxidants
AU - Neu, Heather M.
AU - Yusubov, Mekhman S.
AU - Zhdankin, Viktor Vladimirovich
AU - Nemykin, Victor N.
PY - 2009/12
Y1 - 2009/12
N2 - Two binuclear iron(III) phthalocyanine-(μ-oxodimer) complexes were tested in catalytic oxygenation reactions of several aromatic hydrocarbons using iodosylbenzene (PhIO)n or oligomeric iodosylbenzene sulfate [(PhIO)3SO3]n as the oxidants. Results of this study demonstrate that [(PhIO)3SO3]n is the most reactive oxygenating reagent that can be used as a safe and convenient alternative to the thermally unstable and potentially explosive iodosylbenzene. The pyridine-containing binuclear μ-oxobis-{iron(III)-pyridino[3,4]-9(10), 16(17),23(24)-tri-tertbutyltribenzoporphyrazine} is significantly more active as compared to the traditional μ-oxobis[iron-(III)-2,9(10),16(17),23(24)-tetra- tert-butylphthalocyanine].
AB - Two binuclear iron(III) phthalocyanine-(μ-oxodimer) complexes were tested in catalytic oxygenation reactions of several aromatic hydrocarbons using iodosylbenzene (PhIO)n or oligomeric iodosylbenzene sulfate [(PhIO)3SO3]n as the oxidants. Results of this study demonstrate that [(PhIO)3SO3]n is the most reactive oxygenating reagent that can be used as a safe and convenient alternative to the thermally unstable and potentially explosive iodosylbenzene. The pyridine-containing binuclear μ-oxobis-{iron(III)-pyridino[3,4]-9(10), 16(17),23(24)-tri-tertbutyltribenzoporphyrazine} is significantly more active as compared to the traditional μ-oxobis[iron-(III)-2,9(10),16(17),23(24)-tetra- tert-butylphthalocyanine].
KW - Iodine
KW - Iodosylbenzene
KW - Iodosylbenzene sulfate
KW - Iron phthalocyanine μ-oxodimer
KW - Oxygenation
UR - http://www.scopus.com/inward/record.url?scp=73349089931&partnerID=8YFLogxK
UR - http://www.scopus.com/inward/citedby.url?scp=73349089931&partnerID=8YFLogxK
U2 - 10.1002/adsc.200900705
DO - 10.1002/adsc.200900705
M3 - Article
AN - SCOPUS:73349089931
VL - 351
SP - 3168
EP - 3174
JO - Journal fur Praktische Chemie
JF - Journal fur Praktische Chemie
SN - 1436-9966
IS - 18
ER -