Abstract
Two binuclear iron(III) phthalocyanine-(μ-oxodimer) complexes were tested in catalytic oxygenation reactions of several aromatic hydrocarbons using iodosylbenzene (PhIO)n or oligomeric iodosylbenzene sulfate [(PhIO)3SO3]n as the oxidants. Results of this study demonstrate that [(PhIO)3SO3]n is the most reactive oxygenating reagent that can be used as a safe and convenient alternative to the thermally unstable and potentially explosive iodosylbenzene. The pyridine-containing binuclear μ-oxobis-{iron(III)-pyridino[3,4]-9(10), 16(17),23(24)-tri-tertbutyltribenzoporphyrazine} is significantly more active as compared to the traditional μ-oxobis[iron-(III)-2,9(10),16(17),23(24)-tetra- tert-butylphthalocyanine].
| Original language | English |
|---|---|
| Pages (from-to) | 3168-3174 |
| Number of pages | 7 |
| Journal | Advanced Synthesis and Catalysis |
| Volume | 351 |
| Issue number | 18 |
| DOIs | |
| Publication status | Published - Dec 2009 |
Keywords
- Iodine
- Iodosylbenzene
- Iodosylbenzene sulfate
- Iron phthalocyanine μ-oxodimer
- Oxygenation
ASJC Scopus subject areas
- Catalysis
- Organic Chemistry
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Neu, H. M., Yusubov, M. S., Zhdankin, V. V., & Nemykin, V. N. (2009). Binuclear iron(III) phthalocyanine(μ-oxodimer)-catalyzed oxygenation of aromatic hydrocarbons with iodosylbenzene sulfate and iodosylbenzene as the oxidants. Advanced Synthesis and Catalysis, 351(18), 3168-3174. https://doi.org/10.1002/adsc.200900705