Abstract
Binuclear iron(III) octakis(perfluorophenyl)tetraazaporphyrin μ-oxodimer complex was prepared by the reaction of bis(perfluorophenyl)maleonitrile and Fe(CO)5and tested in catalytic oxygenation reactions of several hydrocarbons in comparison with the analogous non-fluorinated phthalocyanine complexes. Results of the study demonstrate that this complex is a highly efficient catalyst for the oxygenation of anthracene, 2-tert-butylanthracene, naphthalene, 2-methylnaphthalene, phenanthrene, adamantane, and toluene using iodosylbenzene, oligomeric iodosylbenzene sulfate, or Oxone as stoichiometric oxidants.
| Original language | English |
|---|---|
| Pages (from-to) | 5687-5690 |
| Number of pages | 4 |
| Journal | Tetrahedron Letters |
| Volume | 55 |
| Issue number | 41 |
| DOIs | |
| Publication status | Published - 8 Oct 2014 |
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Keywords
- Catalytic oxidation
- Oxygenation
- Phthalocyanines
- Tetraazaporphyrin
ASJC Scopus subject areas
- Biochemistry
- Drug Discovery
- Organic Chemistry
Cite this
Binuclear iron(III) octakis(perfluorophenyl)tetraazaporphyrin μ-oxodimer : A highly efficient catalyst for biomimetic oxygenation reactions. / Yusubov, Mekhman S.; Celik, Cumali; Geraskina, Margarita R.; Yoshimura, Akira; Zhdankin, Viktor Vladimirovich; Nemykin, Victor N.
In: Tetrahedron Letters, Vol. 55, No. 41, 08.10.2014, p. 5687-5690.Research output: Contribution to journal › Article
}
TY - JOUR
T1 - Binuclear iron(III) octakis(perfluorophenyl)tetraazaporphyrin μ-oxodimer
T2 - A highly efficient catalyst for biomimetic oxygenation reactions
AU - Yusubov, Mekhman S.
AU - Celik, Cumali
AU - Geraskina, Margarita R.
AU - Yoshimura, Akira
AU - Zhdankin, Viktor Vladimirovich
AU - Nemykin, Victor N.
PY - 2014/10/8
Y1 - 2014/10/8
N2 - Binuclear iron(III) octakis(perfluorophenyl)tetraazaporphyrin μ-oxodimer complex was prepared by the reaction of bis(perfluorophenyl)maleonitrile and Fe(CO)5and tested in catalytic oxygenation reactions of several hydrocarbons in comparison with the analogous non-fluorinated phthalocyanine complexes. Results of the study demonstrate that this complex is a highly efficient catalyst for the oxygenation of anthracene, 2-tert-butylanthracene, naphthalene, 2-methylnaphthalene, phenanthrene, adamantane, and toluene using iodosylbenzene, oligomeric iodosylbenzene sulfate, or Oxone as stoichiometric oxidants.
AB - Binuclear iron(III) octakis(perfluorophenyl)tetraazaporphyrin μ-oxodimer complex was prepared by the reaction of bis(perfluorophenyl)maleonitrile and Fe(CO)5and tested in catalytic oxygenation reactions of several hydrocarbons in comparison with the analogous non-fluorinated phthalocyanine complexes. Results of the study demonstrate that this complex is a highly efficient catalyst for the oxygenation of anthracene, 2-tert-butylanthracene, naphthalene, 2-methylnaphthalene, phenanthrene, adamantane, and toluene using iodosylbenzene, oligomeric iodosylbenzene sulfate, or Oxone as stoichiometric oxidants.
KW - Catalytic oxidation
KW - Oxygenation
KW - Phthalocyanines
KW - Tetraazaporphyrin
UR - http://www.scopus.com/inward/record.url?scp=84907168780&partnerID=8YFLogxK
UR - http://www.scopus.com/inward/citedby.url?scp=84907168780&partnerID=8YFLogxK
U2 - 10.1016/j.tetlet.2014.08.070
DO - 10.1016/j.tetlet.2014.08.070
M3 - Article
VL - 55
SP - 5687
EP - 5690
JO - Tetrahedron Letters
JF - Tetrahedron Letters
SN - 0040-4039
IS - 41
ER -