Binuclear iron(III) octakis(perfluorophenyl)tetraazaporphyrin μ-oxodimer

A highly efficient catalyst for biomimetic oxygenation reactions

Mekhman S. Yusubov, Cumali Celik, Margarita R. Geraskina, Akira Yoshimura, Viktor Vladimirovich Zhdankin, Victor N. Nemykin

Research output: Contribution to journalArticle

14 Citations (Scopus)

Abstract

Binuclear iron(III) octakis(perfluorophenyl)tetraazaporphyrin μ-oxodimer complex was prepared by the reaction of bis(perfluorophenyl)maleonitrile and Fe(CO)5and tested in catalytic oxygenation reactions of several hydrocarbons in comparison with the analogous non-fluorinated phthalocyanine complexes. Results of the study demonstrate that this complex is a highly efficient catalyst for the oxygenation of anthracene, 2-tert-butylanthracene, naphthalene, 2-methylnaphthalene, phenanthrene, adamantane, and toluene using iodosylbenzene, oligomeric iodosylbenzene sulfate, or Oxone as stoichiometric oxidants.

Original languageEnglish
Pages (from-to)5687-5690
Number of pages4
JournalTetrahedron Letters
Volume55
Issue number41
DOIs
Publication statusPublished - 8 Oct 2014

Fingerprint

Biomimetics
Oxygenation
Iron
Adamantane
Catalysts
Toluene
Carbon Monoxide
Hydrocarbons
Oxidants
Sulfates
iodosobenzene
phthalocyanine
phenanthrene
2-methylnaphthalene
anthracene
naphthalene
potassium peroxymonosulfuric acid

Keywords

  • Catalytic oxidation
  • Oxygenation
  • Phthalocyanines
  • Tetraazaporphyrin

ASJC Scopus subject areas

  • Biochemistry
  • Drug Discovery
  • Organic Chemistry

Cite this

Binuclear iron(III) octakis(perfluorophenyl)tetraazaporphyrin μ-oxodimer : A highly efficient catalyst for biomimetic oxygenation reactions. / Yusubov, Mekhman S.; Celik, Cumali; Geraskina, Margarita R.; Yoshimura, Akira; Zhdankin, Viktor Vladimirovich; Nemykin, Victor N.

In: Tetrahedron Letters, Vol. 55, No. 41, 08.10.2014, p. 5687-5690.

Research output: Contribution to journalArticle

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AU - Geraskina, Margarita R.

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AU - Nemykin, Victor N.

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