Abstract
In most cases the correct estimation of the systematic error of analytical chemistry methods is complicated by the random error, conditioned by irreproducibility of some experimental factors. In stripping voltammetry the appreciable systematic error connected with the residual current (base line) subtraction can appear. The stripping voltammetry feature is absence of information about the base line shape under the peak. The modelling of analytical signal with the addition of the experimental base line for the systematic error estimation of mercury determination by stripping voltammetry with gold-film electrode in the environmental objects are proposed. The systematic error dependences on the relative magnitude of analytical signal of mercury were obtained. The proposed procedure of systematic error compensation allows to reduce the summary error of stripping voltammetry mercury determination in the environmental objects (water samples).
| Original language | English |
|---|---|
| Title of host publication | 5th Korea-Russia International Symposium on Science and Technology - Proceedings: KORUS 2001 |
| Publisher | Institute of Electrical and Electronics Engineers Inc. |
| Pages | 127-128 |
| Number of pages | 2 |
| Volume | 2 |
| ISBN (Print) | 0780370082, 9780780370081 |
| DOIs | |
| Publication status | Published - 2001 |
| Event | 5th Korea-Russia International Symposium on Science and Technology, KORUS 2001 - Tomsk, Russian Federation Duration: 26 Jun 2001 → 3 Jul 2001 |
Other
| Other | 5th Korea-Russia International Symposium on Science and Technology, KORUS 2001 |
|---|---|
| Country | Russian Federation |
| City | Tomsk |
| Period | 26.6.01 → 3.7.01 |
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Keywords
- Analytical signals modelling
- Environmental objects
- Gold-film electrode
- Mercury determination
- Stripping voltammetry
- Systematic error
ASJC Scopus subject areas
- Clinical Biochemistry
- Computer Networks and Communications
- Biotechnology
- Civil and Structural Engineering
- Mechanics of Materials
- Electronic, Optical and Magnetic Materials
- Materials Chemistry
- Surfaces, Coatings and Films
Cite this
Base line subtraction systematic error estimation for mercury determination by stripping voltammetry in environmental objects. / Romanenko, Sergey V.; Larin, Sergey L.; Larina, Ludmila N.
5th Korea-Russia International Symposium on Science and Technology - Proceedings: KORUS 2001. Vol. 2 Institute of Electrical and Electronics Engineers Inc., 2001. p. 127-128 975201.Research output: Chapter in Book/Report/Conference proceeding › Conference contribution
}
TY - GEN
T1 - Base line subtraction systematic error estimation for mercury determination by stripping voltammetry in environmental objects
AU - Romanenko, Sergey V.
AU - Larin, Sergey L.
AU - Larina, Ludmila N.
PY - 2001
Y1 - 2001
N2 - In most cases the correct estimation of the systematic error of analytical chemistry methods is complicated by the random error, conditioned by irreproducibility of some experimental factors. In stripping voltammetry the appreciable systematic error connected with the residual current (base line) subtraction can appear. The stripping voltammetry feature is absence of information about the base line shape under the peak. The modelling of analytical signal with the addition of the experimental base line for the systematic error estimation of mercury determination by stripping voltammetry with gold-film electrode in the environmental objects are proposed. The systematic error dependences on the relative magnitude of analytical signal of mercury were obtained. The proposed procedure of systematic error compensation allows to reduce the summary error of stripping voltammetry mercury determination in the environmental objects (water samples).
AB - In most cases the correct estimation of the systematic error of analytical chemistry methods is complicated by the random error, conditioned by irreproducibility of some experimental factors. In stripping voltammetry the appreciable systematic error connected with the residual current (base line) subtraction can appear. The stripping voltammetry feature is absence of information about the base line shape under the peak. The modelling of analytical signal with the addition of the experimental base line for the systematic error estimation of mercury determination by stripping voltammetry with gold-film electrode in the environmental objects are proposed. The systematic error dependences on the relative magnitude of analytical signal of mercury were obtained. The proposed procedure of systematic error compensation allows to reduce the summary error of stripping voltammetry mercury determination in the environmental objects (water samples).
KW - Analytical signals modelling
KW - Environmental objects
KW - Gold-film electrode
KW - Mercury determination
KW - Stripping voltammetry
KW - Systematic error
UR - http://www.scopus.com/inward/record.url?scp=84961822777&partnerID=8YFLogxK
UR - http://www.scopus.com/inward/citedby.url?scp=84961822777&partnerID=8YFLogxK
U2 - 10.1109/KORUS.2001.975201
DO - 10.1109/KORUS.2001.975201
M3 - Conference contribution
AN - SCOPUS:84961822777
SN - 0780370082
SN - 9780780370081
VL - 2
SP - 127
EP - 128
BT - 5th Korea-Russia International Symposium on Science and Technology - Proceedings: KORUS 2001
PB - Institute of Electrical and Electronics Engineers Inc.
ER -