Abstract
Electron structure changes of SbCl5 on its complexation have been investigated by X-ray fluorescence spectroscopy and compared with corresponding earlier data for SnCl4L2 and TiCl4L2 complexes. X-ray spectral data analysis against the data of the heat of formation of the complexes, Mössbauer effect parameters, derivatographic data, and the valence vibration frequences have permitted an assessment of the complex stability against different factors and have proved donor electron density transfer from the donor to the acceptor to be small. It has been shown that the donor charge effect consists mainly of the acceptor bond polarization.
| Original language | English |
|---|---|
| Pages (from-to) | 543-548 |
| Number of pages | 6 |
| Journal | Heteroatom Chemistry |
| Volume | 9 |
| Issue number | 6 |
| Publication status | Published - 1998 |
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Cite this
Antimonium pentachloride electron density redistribution on complexation. / Dolenko, G. N.; Poleshchuk, O. Kh; Koput, J.
In: Heteroatom Chemistry, Vol. 9, No. 6, 1998, p. 543-548.Research output: Contribution to journal › Article
}
TY - JOUR
T1 - Antimonium pentachloride electron density redistribution on complexation
AU - Dolenko, G. N.
AU - Poleshchuk, O. Kh
AU - Koput, J.
PY - 1998
Y1 - 1998
N2 - Electron structure changes of SbCl5 on its complexation have been investigated by X-ray fluorescence spectroscopy and compared with corresponding earlier data for SnCl4L2 and TiCl4L2 complexes. X-ray spectral data analysis against the data of the heat of formation of the complexes, Mössbauer effect parameters, derivatographic data, and the valence vibration frequences have permitted an assessment of the complex stability against different factors and have proved donor electron density transfer from the donor to the acceptor to be small. It has been shown that the donor charge effect consists mainly of the acceptor bond polarization.
AB - Electron structure changes of SbCl5 on its complexation have been investigated by X-ray fluorescence spectroscopy and compared with corresponding earlier data for SnCl4L2 and TiCl4L2 complexes. X-ray spectral data analysis against the data of the heat of formation of the complexes, Mössbauer effect parameters, derivatographic data, and the valence vibration frequences have permitted an assessment of the complex stability against different factors and have proved donor electron density transfer from the donor to the acceptor to be small. It has been shown that the donor charge effect consists mainly of the acceptor bond polarization.
UR - http://www.scopus.com/inward/record.url?scp=11544318330&partnerID=8YFLogxK
UR - http://www.scopus.com/inward/citedby.url?scp=11544318330&partnerID=8YFLogxK
M3 - Article
AN - SCOPUS:11544318330
VL - 9
SP - 543
EP - 548
JO - Heteroatom Chemistry
JF - Heteroatom Chemistry
SN - 1042-7163
IS - 6
ER -