Antimonium pentachloride electron density redistribution on complexation

Abstract

Electron structure changes of SbCl₅ on its complexation have been investigated by X-ray fluorescence spectroscopy and compared with corresponding earlier data for SnCl₄L₂ and TiCl₄L₂ complexes. X-ray spectral data analysis against the data of the heat of formation of the complexes, Mössbauer effect parameters, derivatographic data, and the valence vibration frequences have permitted an assessment of the complex stability against different factors and have proved donor electron density transfer from the donor to the acceptor to be small. It has been shown that the donor charge effect consists mainly of the acceptor bond polarization.

Original language	English
Pages (from-to)	543-548
Number of pages	6
Journal	Heteroatom Chemistry
Volume	9
Issue number	6
Publication status	Published - 1998

ASJC Scopus subject areas

Chemistry(all)

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abstract = "Electron structure changes of SbCl5 on its complexation have been investigated by X-ray fluorescence spectroscopy and compared with corresponding earlier data for SnCl4L2 and TiCl4L2 complexes. X-ray spectral data analysis against the data of the heat of formation of the complexes, M{\"o}ssbauer effect parameters, derivatographic data, and the valence vibration frequences have permitted an assessment of the complex stability against different factors and have proved donor electron density transfer from the donor to the acceptor to be small. It has been shown that the donor charge effect consists mainly of the acceptor bond polarization.",

author = "Dolenko, {G. N.} and Poleshchuk, {O. Kh} and J. Koput",

year = "1998",

language = "English",

volume = "9",

pages = "543--548",

journal = "Heteroatom Chemistry",

issn = "1042-7163",

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TY - JOUR

T1 - Antimonium pentachloride electron density redistribution on complexation

AU - Dolenko, G. N.

AU - Poleshchuk, O. Kh

AU - Koput, J.

PY - 1998

Y1 - 1998

N2 - Electron structure changes of SbCl5 on its complexation have been investigated by X-ray fluorescence spectroscopy and compared with corresponding earlier data for SnCl4L2 and TiCl4L2 complexes. X-ray spectral data analysis against the data of the heat of formation of the complexes, Mössbauer effect parameters, derivatographic data, and the valence vibration frequences have permitted an assessment of the complex stability against different factors and have proved donor electron density transfer from the donor to the acceptor to be small. It has been shown that the donor charge effect consists mainly of the acceptor bond polarization.

AB - Electron structure changes of SbCl5 on its complexation have been investigated by X-ray fluorescence spectroscopy and compared with corresponding earlier data for SnCl4L2 and TiCl4L2 complexes. X-ray spectral data analysis against the data of the heat of formation of the complexes, Mössbauer effect parameters, derivatographic data, and the valence vibration frequences have permitted an assessment of the complex stability against different factors and have proved donor electron density transfer from the donor to the acceptor to be small. It has been shown that the donor charge effect consists mainly of the acceptor bond polarization.

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VL - 9

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JO - Heteroatom Chemistry

JF - Heteroatom Chemistry

SN - 1042-7163

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ER -

Antimonium pentachloride electron density redistribution on complexation

Abstract

ASJC Scopus subject areas

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