Antifrictional nanocomposites based on chemically modified UHMWPE. Part 3. Comparison of modification effect of compatibilizers on mechanical and tribotechnical properties

Abstract

Two compatibilizers-vinyltrimethoxysilane (VTMS) and maleic anhydride (SMA)-are subjected to comparative analysis in respect to their effect on the mechanical and tribological properties of the composites based on chemically modified UHMWPE. The methods of IR spectroscopy, scanning differential calorimetry, and electronic microscopy are used to study the supermolecular structure of nanocomposites on the base of UHMWPE block-copolymer + 10% UHMWPE-g-VTMS. The mechanical and tribotechnical properties of these nanocomposites are further compared to those of the nanocomposites based on UHMWPE + 10% HDPE-g-SMA. It is shown that the nanocomposites based on block-copolymers with the mentioned compatibilizers have similar (spherulitic) structure and roughly equal wear resistance, being close to those of the composites based on the non-modified polymer. The wear resistance of the nanocomposites on the base of UHMWPE depends on whether the fillers are present and distributed evenly in the matrix. This defines the crystallization conditions and, as a consequence, the type of the formed supermolecular structure.

Original language	English
Pages (from-to)	47-52
Number of pages	6
Journal	Journal of Friction and Wear
Volume	33
Issue number	1
DOIs	https://doi.org/10.3103/S1068366612010096
Publication status	Published - Feb 2012

Keywords

chemical modification
compatibilizer
grafting
mechanical properties
nanofillers
super-high molecular weight polyethylene
supermolecular structure
wear resistance

ASJC Scopus subject areas

Mechanics of Materials
Surfaces, Coatings and Films

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10.3103/S1068366612010096

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Panin, S. V., Kornienko, L. A., Piriyaon, S., Sonjaitham, N., Ivanova, L. R., Shilko, S. V., Pleskachevskii, Y. M., & Orlov, V. M. (2012). Antifrictional nanocomposites based on chemically modified UHMWPE. Part 3. Comparison of modification effect of compatibilizers on mechanical and tribotechnical properties. Journal of Friction and Wear, 33(1), 47-52. https://doi.org/10.3103/S1068366612010096

Antifrictional nanocomposites based on chemically modified UHMWPE. Part 3. Comparison of modification effect of compatibilizers on mechanical and tribotechnical properties. / Panin, S. V.; Kornienko, L. A.; Piriyaon, S.; Sonjaitham, N.; Ivanova, L. R.; Shilko, S. V.; Pleskachevskii, Yu M.; Orlov, V. M.

In: Journal of Friction and Wear, Vol. 33, No. 1, 02.2012, p. 47-52.

Research output: Contribution to journal › Article

Panin, SV, Kornienko, LA, Piriyaon, S, Sonjaitham, N, Ivanova, LR, Shilko, SV, Pleskachevskii, YM & Orlov, VM 2012, 'Antifrictional nanocomposites based on chemically modified UHMWPE. Part 3. Comparison of modification effect of compatibilizers on mechanical and tribotechnical properties', Journal of Friction and Wear, vol. 33, no. 1, pp. 47-52. https://doi.org/10.3103/S1068366612010096

Panin, S. V. ; Kornienko, L. A. ; Piriyaon, S. ; Sonjaitham, N. ; Ivanova, L. R. ; Shilko, S. V. ; Pleskachevskii, Yu M. ; Orlov, V. M. / Antifrictional nanocomposites based on chemically modified UHMWPE. Part 3. Comparison of modification effect of compatibilizers on mechanical and tribotechnical properties. In: Journal of Friction and Wear. 2012 ; Vol. 33, No. 1. pp. 47-52.

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title = "Antifrictional nanocomposites based on chemically modified UHMWPE. Part 3. Comparison of modification effect of compatibilizers on mechanical and tribotechnical properties",

abstract = "Two compatibilizers-vinyltrimethoxysilane (VTMS) and maleic anhydride (SMA)-are subjected to comparative analysis in respect to their effect on the mechanical and tribological properties of the composites based on chemically modified UHMWPE. The methods of IR spectroscopy, scanning differential calorimetry, and electronic microscopy are used to study the supermolecular structure of nanocomposites on the base of UHMWPE block-copolymer + 10% UHMWPE-g-VTMS. The mechanical and tribotechnical properties of these nanocomposites are further compared to those of the nanocomposites based on UHMWPE + 10% HDPE-g-SMA. It is shown that the nanocomposites based on block-copolymers with the mentioned compatibilizers have similar (spherulitic) structure and roughly equal wear resistance, being close to those of the composites based on the non-modified polymer. The wear resistance of the nanocomposites on the base of UHMWPE depends on whether the fillers are present and distributed evenly in the matrix. This defines the crystallization conditions and, as a consequence, the type of the formed supermolecular structure.",

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author = "Panin, {S. V.} and Kornienko, {L. A.} and S. Piriyaon and N. Sonjaitham and Ivanova, {L. R.} and Shilko, {S. V.} and Pleskachevskii, {Yu M.} and Orlov, {V. M.}",

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AU - Piriyaon, S.

AU - Sonjaitham, N.

AU - Ivanova, L. R.

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AB - Two compatibilizers-vinyltrimethoxysilane (VTMS) and maleic anhydride (SMA)-are subjected to comparative analysis in respect to their effect on the mechanical and tribological properties of the composites based on chemically modified UHMWPE. The methods of IR spectroscopy, scanning differential calorimetry, and electronic microscopy are used to study the supermolecular structure of nanocomposites on the base of UHMWPE block-copolymer + 10% UHMWPE-g-VTMS. The mechanical and tribotechnical properties of these nanocomposites are further compared to those of the nanocomposites based on UHMWPE + 10% HDPE-g-SMA. It is shown that the nanocomposites based on block-copolymers with the mentioned compatibilizers have similar (spherulitic) structure and roughly equal wear resistance, being close to those of the composites based on the non-modified polymer. The wear resistance of the nanocomposites on the base of UHMWPE depends on whether the fillers are present and distributed evenly in the matrix. This defines the crystallization conditions and, as a consequence, the type of the formed supermolecular structure.

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