Abstract
Presented are the results on the study of insoluble products obtained at autoclave thermolysis of resins and asphaltenes of the oil from the Usinskoye oil field in an argon atmosphere at 160-650°C. A high yielded chloroform-insoluble thermolysis product obtained from the resins of heavy high-sulfur oil at 250°C significantly differs from products obtained from resins and asphaltenes at 450 and 650°C but according to the results of Rock Eval and 'on-line' flash pyrolysis (600°C, 20 s), and elemental analysis it is similar to 'asphaltene-like' substances. Their formation is probably due to the cleavage at 250°C of the most labile S-S or C-S bonds in the resin molecules followed by generation and recombination of macroradicals. The thermal destruction of these substances at higher temperatures (450 and 650°C) is accompanied by the formation of more carbonized coke-like products.
| Original language | English |
|---|---|
| Title of host publication | Proceedings of the Advanced Materials with Hierarchical Structure for New Technologies and Reliable Structures |
| Editors | Vasily M. Fomin, Victor E. Panin, Sergey G. Psakhie |
| Publisher | American Institute of Physics Inc. |
| ISBN (Electronic) | 9780735417779 |
| DOIs | |
| Publication status | Published - 12 Dec 2018 |
| Event | International Symposium on Hierarchical Materials: Development and Applications for New Technologies and Reliable Structures 2018 - Tomsk, Russian Federation Duration: 1 Oct 2018 → 5 Oct 2018 |
Publication series
| Name | AIP Conference Proceedings |
|---|---|
| Volume | 2051 |
| ISSN (Print) | 0094-243X |
| ISSN (Electronic) | 1551-7616 |
Conference
| Conference | International Symposium on Hierarchical Materials: Development and Applications for New Technologies and Reliable Structures 2018 |
|---|---|
| Country | Russian Federation |
| City | Tomsk |
| Period | 1.10.18 → 5.10.18 |
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ASJC Scopus subject areas
- Physics and Astronomy(all)
Cite this
Analytical pyrolysis of insoluble products obtained by thermolysis of resins and asphaltenes of the oil from the Usinskoye oil field. / Antipenko, Vladimir R.; Grin'Ko, Andrey A.; Golovko, Anatoly K.; Melenevskiy, Vasily N.
Proceedings of the Advanced Materials with Hierarchical Structure for New Technologies and Reliable Structures. ed. / Vasily M. Fomin; Victor E. Panin; Sergey G. Psakhie. American Institute of Physics Inc., 2018. 020019 (AIP Conference Proceedings; Vol. 2051).Research output: Chapter in Book/Report/Conference proceeding › Conference contribution
}
TY - GEN
T1 - Analytical pyrolysis of insoluble products obtained by thermolysis of resins and asphaltenes of the oil from the Usinskoye oil field
AU - Antipenko, Vladimir R.
AU - Grin'Ko, Andrey A.
AU - Golovko, Anatoly K.
AU - Melenevskiy, Vasily N.
PY - 2018/12/12
Y1 - 2018/12/12
N2 - Presented are the results on the study of insoluble products obtained at autoclave thermolysis of resins and asphaltenes of the oil from the Usinskoye oil field in an argon atmosphere at 160-650°C. A high yielded chloroform-insoluble thermolysis product obtained from the resins of heavy high-sulfur oil at 250°C significantly differs from products obtained from resins and asphaltenes at 450 and 650°C but according to the results of Rock Eval and 'on-line' flash pyrolysis (600°C, 20 s), and elemental analysis it is similar to 'asphaltene-like' substances. Their formation is probably due to the cleavage at 250°C of the most labile S-S or C-S bonds in the resin molecules followed by generation and recombination of macroradicals. The thermal destruction of these substances at higher temperatures (450 and 650°C) is accompanied by the formation of more carbonized coke-like products.
AB - Presented are the results on the study of insoluble products obtained at autoclave thermolysis of resins and asphaltenes of the oil from the Usinskoye oil field in an argon atmosphere at 160-650°C. A high yielded chloroform-insoluble thermolysis product obtained from the resins of heavy high-sulfur oil at 250°C significantly differs from products obtained from resins and asphaltenes at 450 and 650°C but according to the results of Rock Eval and 'on-line' flash pyrolysis (600°C, 20 s), and elemental analysis it is similar to 'asphaltene-like' substances. Their formation is probably due to the cleavage at 250°C of the most labile S-S or C-S bonds in the resin molecules followed by generation and recombination of macroradicals. The thermal destruction of these substances at higher temperatures (450 and 650°C) is accompanied by the formation of more carbonized coke-like products.
UR - http://www.scopus.com/inward/record.url?scp=85059022718&partnerID=8YFLogxK
UR - http://www.scopus.com/inward/citedby.url?scp=85059022718&partnerID=8YFLogxK
U2 - 10.1063/1.5083262
DO - 10.1063/1.5083262
M3 - Conference contribution
AN - SCOPUS:85059022718
T3 - AIP Conference Proceedings
BT - Proceedings of the Advanced Materials with Hierarchical Structure for New Technologies and Reliable Structures
A2 - Fomin, Vasily M.
A2 - Panin, Victor E.
A2 - Psakhie, Sergey G.
PB - American Institute of Physics Inc.
ER -