Analytical pyrolysis of insoluble products obtained by thermolysis of resins and asphaltenes of the oil from the Usinskoye oil field

Vladimir R. Antipenko, Andrey A. Grin'Ko, Anatoly K. Golovko, Vasily N. Melenevskiy

Research output: Chapter in Book/Report/Conference proceedingConference contribution

Abstract

Presented are the results on the study of insoluble products obtained at autoclave thermolysis of resins and asphaltenes of the oil from the Usinskoye oil field in an argon atmosphere at 160-650°C. A high yielded chloroform-insoluble thermolysis product obtained from the resins of heavy high-sulfur oil at 250°C significantly differs from products obtained from resins and asphaltenes at 450 and 650°C but according to the results of Rock Eval and 'on-line' flash pyrolysis (600°C, 20 s), and elemental analysis it is similar to 'asphaltene-like' substances. Their formation is probably due to the cleavage at 250°C of the most labile S-S or C-S bonds in the resin molecules followed by generation and recombination of macroradicals. The thermal destruction of these substances at higher temperatures (450 and 650°C) is accompanied by the formation of more carbonized coke-like products.

Original languageEnglish
Title of host publicationProceedings of the Advanced Materials with Hierarchical Structure for New Technologies and Reliable Structures
EditorsVasily M. Fomin, Victor E. Panin, Sergey G. Psakhie
PublisherAmerican Institute of Physics Inc.
ISBN (Electronic)9780735417779
DOIs
Publication statusPublished - 12 Dec 2018
EventInternational Symposium on Hierarchical Materials: Development and Applications for New Technologies and Reliable Structures 2018 - Tomsk, Russian Federation
Duration: 1 Oct 20185 Oct 2018

Publication series

NameAIP Conference Proceedings
Volume2051
ISSN (Print)0094-243X
ISSN (Electronic)1551-7616

Conference

ConferenceInternational Symposium on Hierarchical Materials: Development and Applications for New Technologies and Reliable Structures 2018
CountryRussian Federation
CityTomsk
Period1.10.185.10.18

Fingerprint

asphaltenes
oil fields
resins
pyrolysis
oils
products
autoclaves
coke
chloroform
destruction
flash
cleavage
sulfur
argon
rocks
atmospheres
molecules

ASJC Scopus subject areas

  • Physics and Astronomy(all)

Cite this

Antipenko, V. R., Grin'Ko, A. A., Golovko, A. K., & Melenevskiy, V. N. (2018). Analytical pyrolysis of insoluble products obtained by thermolysis of resins and asphaltenes of the oil from the Usinskoye oil field. In V. M. Fomin, V. E. Panin, & S. G. Psakhie (Eds.), Proceedings of the Advanced Materials with Hierarchical Structure for New Technologies and Reliable Structures [020019] (AIP Conference Proceedings; Vol. 2051). American Institute of Physics Inc.. https://doi.org/10.1063/1.5083262

Analytical pyrolysis of insoluble products obtained by thermolysis of resins and asphaltenes of the oil from the Usinskoye oil field. / Antipenko, Vladimir R.; Grin'Ko, Andrey A.; Golovko, Anatoly K.; Melenevskiy, Vasily N.

Proceedings of the Advanced Materials with Hierarchical Structure for New Technologies and Reliable Structures. ed. / Vasily M. Fomin; Victor E. Panin; Sergey G. Psakhie. American Institute of Physics Inc., 2018. 020019 (AIP Conference Proceedings; Vol. 2051).

Research output: Chapter in Book/Report/Conference proceedingConference contribution

Antipenko, VR, Grin'Ko, AA, Golovko, AK & Melenevskiy, VN 2018, Analytical pyrolysis of insoluble products obtained by thermolysis of resins and asphaltenes of the oil from the Usinskoye oil field. in VM Fomin, VE Panin & SG Psakhie (eds), Proceedings of the Advanced Materials with Hierarchical Structure for New Technologies and Reliable Structures., 020019, AIP Conference Proceedings, vol. 2051, American Institute of Physics Inc., International Symposium on Hierarchical Materials: Development and Applications for New Technologies and Reliable Structures 2018, Tomsk, Russian Federation, 1.10.18. https://doi.org/10.1063/1.5083262
Antipenko VR, Grin'Ko AA, Golovko AK, Melenevskiy VN. Analytical pyrolysis of insoluble products obtained by thermolysis of resins and asphaltenes of the oil from the Usinskoye oil field. In Fomin VM, Panin VE, Psakhie SG, editors, Proceedings of the Advanced Materials with Hierarchical Structure for New Technologies and Reliable Structures. American Institute of Physics Inc. 2018. 020019. (AIP Conference Proceedings). https://doi.org/10.1063/1.5083262
Antipenko, Vladimir R. ; Grin'Ko, Andrey A. ; Golovko, Anatoly K. ; Melenevskiy, Vasily N. / Analytical pyrolysis of insoluble products obtained by thermolysis of resins and asphaltenes of the oil from the Usinskoye oil field. Proceedings of the Advanced Materials with Hierarchical Structure for New Technologies and Reliable Structures. editor / Vasily M. Fomin ; Victor E. Panin ; Sergey G. Psakhie. American Institute of Physics Inc., 2018. (AIP Conference Proceedings).
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