Abstract
The Kα shifts in the X-ray fluorescence spectra of the aluminum tribromide complexes with phosphorus-containing ligands are calculated. The analysis of the complexation-induced changes in the dipole moments of donors is performed. A comparison of the dipole moments, calculated for the complexes using the PM3 and AM1 methods, with those obtained by the vector scheme and molecular mechanics method shows that the changes in the dipole moment of a donor should be taken into account when considering the complexation-induced increase in dipole moments.
| Original language | English |
|---|---|
| Pages (from-to) | 694-697 |
| Number of pages | 4 |
| Journal | Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya |
| Volume | 23 |
| Issue number | 10 |
| Publication status | Published - Oct 1997 |
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ASJC Scopus subject areas
- Inorganic Chemistry
Cite this
Analysis of the changes in dipole moments upon complexation. / Poleshchuk, O. Kh; Dolenko, G. N.; Latoshinska, I.
In: Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya, Vol. 23, No. 10, 10.1997, p. 694-697.Research output: Contribution to journal › Article
}
TY - JOUR
T1 - Analysis of the changes in dipole moments upon complexation
AU - Poleshchuk, O. Kh
AU - Dolenko, G. N.
AU - Latoshinska, I.
PY - 1997/10
Y1 - 1997/10
N2 - The Kα shifts in the X-ray fluorescence spectra of the aluminum tribromide complexes with phosphorus-containing ligands are calculated. The analysis of the complexation-induced changes in the dipole moments of donors is performed. A comparison of the dipole moments, calculated for the complexes using the PM3 and AM1 methods, with those obtained by the vector scheme and molecular mechanics method shows that the changes in the dipole moment of a donor should be taken into account when considering the complexation-induced increase in dipole moments.
AB - The Kα shifts in the X-ray fluorescence spectra of the aluminum tribromide complexes with phosphorus-containing ligands are calculated. The analysis of the complexation-induced changes in the dipole moments of donors is performed. A comparison of the dipole moments, calculated for the complexes using the PM3 and AM1 methods, with those obtained by the vector scheme and molecular mechanics method shows that the changes in the dipole moment of a donor should be taken into account when considering the complexation-induced increase in dipole moments.
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UR - http://www.scopus.com/inward/citedby.url?scp=27644480544&partnerID=8YFLogxK
M3 - Article
AN - SCOPUS:27644480544
VL - 23
SP - 694
EP - 697
JO - Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya
JF - Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya
SN - 1070-3284
IS - 10
ER -