Analysis of the changes in dipole moments upon complexation

O. Kh Poleshchuk, G. N. Dolenko, I. Latoshinska

    Research output: Contribution to journalArticle

    Abstract

    The Kα shifts in the X-ray fluorescence spectra of the aluminum tribromide complexes with phosphorus-containing ligands are calculated. The analysis of the complexation-induced changes in the dipole moments of donors is performed. A comparison of the dipole moments, calculated for the complexes using the PM3 and AM1 methods, with those obtained by the vector scheme and molecular mechanics method shows that the changes in the dipole moment of a donor should be taken into account when considering the complexation-induced increase in dipole moments.

    Original languageEnglish
    Pages (from-to)694-697
    Number of pages4
    JournalRussian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya
    Volume23
    Issue number10
    Publication statusPublished - Oct 1997

    ASJC Scopus subject areas

    • Inorganic Chemistry

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