The Kα shifts in the X-ray fluorescence spectra of the aluminum tribromide complexes with phosphorus-containing ligands are calculated. The analysis of the complexation-induced changes in the dipole moments of donors is performed. A comparison of the dipole moments, calculated for the complexes using the PM3 and AM1 methods, with those obtained by the vector scheme and molecular mechanics method shows that the changes in the dipole moment of a donor should be taken into account when considering the complexation-induced increase in dipole moments.
|Number of pages||4|
|Journal||Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya|
|Publication status||Published - Oct 1997|
ASJC Scopus subject areas
- Inorganic Chemistry