An x-ray diffraction study of the reaction products of copper(II) chloride with N1,N2-BIS(5-methylpyridin-2-YL)oxalamide

D. A. Piryazev, A. S. Zhilin, A. I. Smolentsev, A. V. Virovets, S. F. Vasilevskii, L. G. Lavrenova

Research output: Contribution to journalArticle

1 Citation (Scopus)

Abstract

Polymeric complexes of [Cu2Cl2L2]∞ copper(I) chloride (1) (L = N1,N2-bis(5-methylpyridin-2- yl)- oxalamide)) and {[Cu2(C2O4)Cl 2L](L)·2H2O}∞ copper(II) chloride (2) are obtained. The complexes are studied by powder and single crystal XRD. It is found that during the reaction of L with copper(II) chloride in the formation of complex 1 copper(II) is reduced to copper(I), while the formation of complex 2 is accompanied by the hydrolysis of the ligand.

Original languageEnglish
Pages (from-to)376-382
Number of pages7
JournalJournal of Structural Chemistry
Volume52
Issue number2
DOIs
Publication statusPublished - 1 Jan 2011
Externally publishedYes

Fingerprint

Reaction products
reaction products
Copper
x ray diffraction
Diffraction
chlorides
X rays
copper
Powders
Hydrolysis
Single crystals
Ligands
hydrolysis
cupric chloride
ligands
single crystals
crystals
cuprous chloride

Keywords

  • Complexes
  • Coordination polymers
  • copper(II)
  • Singe crystal and powder XRD

ASJC Scopus subject areas

  • Physical and Theoretical Chemistry
  • Inorganic Chemistry
  • Materials Chemistry

Cite this

An x-ray diffraction study of the reaction products of copper(II) chloride with N1,N2-BIS(5-methylpyridin-2-YL)oxalamide. / Piryazev, D. A.; Zhilin, A. S.; Smolentsev, A. I.; Virovets, A. V.; Vasilevskii, S. F.; Lavrenova, L. G.

In: Journal of Structural Chemistry, Vol. 52, No. 2, 01.01.2011, p. 376-382.

Research output: Contribution to journalArticle

Piryazev, D. A. ; Zhilin, A. S. ; Smolentsev, A. I. ; Virovets, A. V. ; Vasilevskii, S. F. ; Lavrenova, L. G. / An x-ray diffraction study of the reaction products of copper(II) chloride with N1,N2-BIS(5-methylpyridin-2-YL)oxalamide. In: Journal of Structural Chemistry. 2011 ; Vol. 52, No. 2. pp. 376-382.
@article{02c2ed1b05e74d50b4826f8061307a28,
title = "An x-ray diffraction study of the reaction products of copper(II) chloride with N1,N2-BIS(5-methylpyridin-2-YL)oxalamide",
abstract = "Polymeric complexes of [Cu2Cl2L2]∞ copper(I) chloride (1) (L = N1,N2-bis(5-methylpyridin-2- yl)- oxalamide)) and {[Cu2(C2O4)Cl 2L](L)·2H2O}∞ copper(II) chloride (2) are obtained. The complexes are studied by powder and single crystal XRD. It is found that during the reaction of L with copper(II) chloride in the formation of complex 1 copper(II) is reduced to copper(I), while the formation of complex 2 is accompanied by the hydrolysis of the ligand.",
keywords = "Complexes, Coordination polymers, copper(II), Singe crystal and powder XRD",
author = "Piryazev, {D. A.} and Zhilin, {A. S.} and Smolentsev, {A. I.} and Virovets, {A. V.} and Vasilevskii, {S. F.} and Lavrenova, {L. G.}",
year = "2011",
month = "1",
day = "1",
doi = "10.1134/S0022476611020193",
language = "English",
volume = "52",
pages = "376--382",
journal = "Journal of Structural Chemistry",
issn = "0022-4766",
publisher = "Springer GmbH & Co, Auslieferungs-Gesellschaf",
number = "2",

}

TY - JOUR

T1 - An x-ray diffraction study of the reaction products of copper(II) chloride with N1,N2-BIS(5-methylpyridin-2-YL)oxalamide

AU - Piryazev, D. A.

AU - Zhilin, A. S.

AU - Smolentsev, A. I.

AU - Virovets, A. V.

AU - Vasilevskii, S. F.

AU - Lavrenova, L. G.

PY - 2011/1/1

Y1 - 2011/1/1

N2 - Polymeric complexes of [Cu2Cl2L2]∞ copper(I) chloride (1) (L = N1,N2-bis(5-methylpyridin-2- yl)- oxalamide)) and {[Cu2(C2O4)Cl 2L](L)·2H2O}∞ copper(II) chloride (2) are obtained. The complexes are studied by powder and single crystal XRD. It is found that during the reaction of L with copper(II) chloride in the formation of complex 1 copper(II) is reduced to copper(I), while the formation of complex 2 is accompanied by the hydrolysis of the ligand.

AB - Polymeric complexes of [Cu2Cl2L2]∞ copper(I) chloride (1) (L = N1,N2-bis(5-methylpyridin-2- yl)- oxalamide)) and {[Cu2(C2O4)Cl 2L](L)·2H2O}∞ copper(II) chloride (2) are obtained. The complexes are studied by powder and single crystal XRD. It is found that during the reaction of L with copper(II) chloride in the formation of complex 1 copper(II) is reduced to copper(I), while the formation of complex 2 is accompanied by the hydrolysis of the ligand.

KW - Complexes

KW - Coordination polymers

KW - copper(II)

KW - Singe crystal and powder XRD

UR - http://www.scopus.com/inward/record.url?scp=80054744806&partnerID=8YFLogxK

UR - http://www.scopus.com/inward/citedby.url?scp=80054744806&partnerID=8YFLogxK

U2 - 10.1134/S0022476611020193

DO - 10.1134/S0022476611020193

M3 - Article

VL - 52

SP - 376

EP - 382

JO - Journal of Structural Chemistry

JF - Journal of Structural Chemistry

SN - 0022-4766

IS - 2

ER -