An x-ray diffraction study of the reaction products of copper(II) chloride with N1,N2-BIS(5-methylpyridin-2-YL)oxalamide

D. A. Piryazev, A. S. Zhilin, A. I. Smolentsev, A. V. Virovets, S. F. Vasilevskii, L. G. Lavrenova

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1 Citation (Scopus)

Abstract

Polymeric complexes of [Cu2Cl2L2]∞ copper(I) chloride (1) (L = N1,N2-bis(5-methylpyridin-2- yl)- oxalamide)) and {[Cu2(C2O4)Cl 2L](L)·2H2O}∞ copper(II) chloride (2) are obtained. The complexes are studied by powder and single crystal XRD. It is found that during the reaction of L with copper(II) chloride in the formation of complex 1 copper(II) is reduced to copper(I), while the formation of complex 2 is accompanied by the hydrolysis of the ligand.

Original languageEnglish
Pages (from-to)376-382
Number of pages7
JournalJournal of Structural Chemistry
Volume52
Issue number2
DOIs
Publication statusPublished - 1 Jan 2011
Externally publishedYes

Keywords

  • Complexes
  • Coordination polymers
  • copper(II)
  • Singe crystal and powder XRD

ASJC Scopus subject areas

  • Physical and Theoretical Chemistry
  • Inorganic Chemistry
  • Materials Chemistry

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