Abstract
The deactivation of catalysts by coke-forming structures in the dehydrogenation of higher n-paraffins is discussed. The patterns of coke formation on a catalyst subject to process conditions are presented. A mathematical model of the process is described to show its adequacy. A calculation algorithm for the optimum mode of operation of a dehydrogenation catalyst is constructed, and the calculation results are given. Dehydrogenation catalysts of different brands are compared with respect to several parameters (coke formation on catalysts, the yield of the reaction by-product, and the dynamics of temperature rise in the reactor). The model can be used to estimate the efficiencies of catalysts in a cycle and to compare them.
| Original language | English |
|---|---|
| Pages (from-to) | 360-367 |
| Number of pages | 8 |
| Journal | Catalysis in Industry |
| Volume | 2 |
| Issue number | 4 |
| DOIs | |
| Publication status | Published - Dec 2010 |
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Keywords
- deactivation
- dehydrogenation
- integrated criterion of catalyst efficiency
- linear alkylbenzene
- mathematical model
- optimum activity
- Pt catalyst
ASJC Scopus subject areas
- Catalysis
Cite this
An integrated criterion of efficiency for Pt catalysts in the dehydrogenation of higher n-paraffins. / Romanovskiy, R. V.; Frantsina, E. V.; Youriev, E. M.; Ivashkina, E. N.; Ivanchina, E. D.; Kravtsov, A. V.
In: Catalysis in Industry, Vol. 2, No. 4, 12.2010, p. 360-367.Research output: Contribution to journal › Article
}
TY - JOUR
T1 - An integrated criterion of efficiency for Pt catalysts in the dehydrogenation of higher n-paraffins
AU - Romanovskiy, R. V.
AU - Frantsina, E. V.
AU - Youriev, E. M.
AU - Ivashkina, E. N.
AU - Ivanchina, E. D.
AU - Kravtsov, A. V.
PY - 2010/12
Y1 - 2010/12
N2 - The deactivation of catalysts by coke-forming structures in the dehydrogenation of higher n-paraffins is discussed. The patterns of coke formation on a catalyst subject to process conditions are presented. A mathematical model of the process is described to show its adequacy. A calculation algorithm for the optimum mode of operation of a dehydrogenation catalyst is constructed, and the calculation results are given. Dehydrogenation catalysts of different brands are compared with respect to several parameters (coke formation on catalysts, the yield of the reaction by-product, and the dynamics of temperature rise in the reactor). The model can be used to estimate the efficiencies of catalysts in a cycle and to compare them.
AB - The deactivation of catalysts by coke-forming structures in the dehydrogenation of higher n-paraffins is discussed. The patterns of coke formation on a catalyst subject to process conditions are presented. A mathematical model of the process is described to show its adequacy. A calculation algorithm for the optimum mode of operation of a dehydrogenation catalyst is constructed, and the calculation results are given. Dehydrogenation catalysts of different brands are compared with respect to several parameters (coke formation on catalysts, the yield of the reaction by-product, and the dynamics of temperature rise in the reactor). The model can be used to estimate the efficiencies of catalysts in a cycle and to compare them.
KW - deactivation
KW - dehydrogenation
KW - integrated criterion of catalyst efficiency
KW - linear alkylbenzene
KW - mathematical model
KW - optimum activity
KW - Pt catalyst
UR - http://www.scopus.com/inward/record.url?scp=79251634208&partnerID=8YFLogxK
UR - http://www.scopus.com/inward/citedby.url?scp=79251634208&partnerID=8YFLogxK
U2 - 10.1134/S2070050410040100
DO - 10.1134/S2070050410040100
M3 - Article
VL - 2
SP - 360
EP - 367
JO - Catalysis in Industry
JF - Catalysis in Industry
SN - 2070-0504
IS - 4
ER -