ADSORPTION OF Cs** plus AND Zn**2** plus CATIONS ON SMOOTH PLATINUM, IRIDIUM, AND RHODIUM ELECTRODES.

M. S. Chemeris, N. A. Kolpakova, A. G. Stromberg, Yu B. Vasil'ev

Research output: Chapter in Book/Report/Conference proceedingChapter

Abstract

It is shown that the nature of the influence of the adsorbed cations on the adsorption of hydrogen changes on going from one metal to another, depends on the strength of the metal-hydrogen bond, and is determined by the competition between the cation and hydrogen for the surface and by electrostatic factors, that is, the polarity of the metal-hydrogen bond and the degree of ionic character of the bond between the metal and the adsorbed cation. The range of potentials of the predominant adsorption of the cations, on going from platinum to iridium and rhodium, becomes narrower and is determined by the position of the point of zero free charge for the given metal.

Original languageEnglish
Title of host publicationSov Electrochem
Pages49-54
Number of pages6
Volume12
Edition1
Publication statusPublished - Jan 1976

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Iridium
Rhodium
Platinum
Positive ions
Electrodes
Metals
Hydrogen bonds
Adsorption
Hydrogen
Electrostatics

ASJC Scopus subject areas

  • Engineering(all)

Cite this

Chemeris, M. S., Kolpakova, N. A., Stromberg, A. G., & Vasil'ev, Y. B. (1976). ADSORPTION OF Cs** plus AND Zn**2** plus CATIONS ON SMOOTH PLATINUM, IRIDIUM, AND RHODIUM ELECTRODES. In Sov Electrochem (1 ed., Vol. 12, pp. 49-54)

ADSORPTION OF Cs** plus AND Zn**2** plus CATIONS ON SMOOTH PLATINUM, IRIDIUM, AND RHODIUM ELECTRODES. / Chemeris, M. S.; Kolpakova, N. A.; Stromberg, A. G.; Vasil'ev, Yu B.

Sov Electrochem. Vol. 12 1. ed. 1976. p. 49-54.

Research output: Chapter in Book/Report/Conference proceedingChapter

Chemeris, MS, Kolpakova, NA, Stromberg, AG & Vasil'ev, YB 1976, ADSORPTION OF Cs** plus AND Zn**2** plus CATIONS ON SMOOTH PLATINUM, IRIDIUM, AND RHODIUM ELECTRODES. in Sov Electrochem. 1 edn, vol. 12, pp. 49-54.
Chemeris MS, Kolpakova NA, Stromberg AG, Vasil'ev YB. ADSORPTION OF Cs** plus AND Zn**2** plus CATIONS ON SMOOTH PLATINUM, IRIDIUM, AND RHODIUM ELECTRODES. In Sov Electrochem. 1 ed. Vol. 12. 1976. p. 49-54
Chemeris, M. S. ; Kolpakova, N. A. ; Stromberg, A. G. ; Vasil'ev, Yu B. / ADSORPTION OF Cs** plus AND Zn**2** plus CATIONS ON SMOOTH PLATINUM, IRIDIUM, AND RHODIUM ELECTRODES. Sov Electrochem. Vol. 12 1. ed. 1976. pp. 49-54
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