A thermoanalysis of phase transformations and linear shrinkage kinetics of ceramics made from ultrafine plasmochemical ZrO2(Y)-Al 2O3 powders

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Abstract

The methods of X-ray diffraction analysis, thermogravimetric analysis, differential scanning calorimetry, and dilatometry are used to study special features of the structural-phase state of the 80 mass% ZrO2(Y)-20 mass% Al2O3 plasmochemical powders (PCPs) and their effects on the sintering of composite ceramics. It is revealed that the ZrO 2(Y)-Al2O3 powder composite represents a mechanical mixture containing crystalline tetragonal zirconium dioxide and aluminum oxide nanoparticles, the latter found in an amorphous state and partially included into the ZrO2(Y) lattice, thus forming metastable solid solutions of variable composition. Heating of the composite powder within the temperature range 740-1,000 C reveals an exothermal effect associated with decomposition of metastable states of aluminum oxide. This is accompanied by the formation of the corundum-phase nuclei having subcritical dimensions. They achieve the critical sizes at higher temperatures T > 1200 C, when α-Al2O3 is finally crystallized. The shrinkage response of the powder compacts during non-isothermal sintering is measured in a sensitive dilatometer. It is shown that the shrinkage curve consists of several stages that closely correlate with the concurrent structural-phase transformation in the composite ZrO2(Y)-Al2O3 powder mixture. The decisive contribution into shrinkage during non-isothermal sintering of composite comes from the high-temperature stages with the maximum shrinkage rate at the temperatures 1,250 and 1,550 C. It is found out that the regime of sintering the ultrafine PCPs (T = 1,600 C, t = 1 h) allows producing composite ceramic materials with a porosity of Q ≈ (5-7) %, microhardness H v = 12.3 GPa, and crack resistance š 1c = (10-11) MPa m0.5.

Original languageEnglish
Pages (from-to)1439-1445
Number of pages7
JournalJournal of Thermal Analysis and Calorimetry
Volume115
Issue number2
DOIs
Publication statusPublished - 1 Feb 2014

Keywords

  • Alumina toughened zirconia ceramics
  • Dilatometry
  • DSC
  • Phase transformations
  • Shrinkage
  • Sintering
  • TG

ASJC Scopus subject areas

  • Condensed Matter Physics
  • Physical and Theoretical Chemistry

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