Abstract
An atomic probe technique in conjunction with an atomic attenuator was used to study the recombination of hydrogen atoms on the surface of Zn2SiO4-Mn composition. The recombination of hydrogen atoms was found to occur via both the Rideal-Eley and Langmuir-Hinshelwood mechanisms. The contributions of these mechanisms to the total reaction rate were determined for various experimental conditions. The reaction rate was calculated from a nonequilibrium luminescence of the crystalline catalyst. This phenomenon is a variety of heterogeneous chemiluminescence, more specifically, radical-recombination luminescence.
| Original language | English |
|---|---|
| Pages (from-to) | 1729-1734 |
| Number of pages | 6 |
| Journal | Russian Journal of Physical Chemistry A |
| Volume | 70 |
| Issue number | 10 |
| Publication status | Published - Oct 1996 |
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ASJC Scopus subject areas
- Physical and Theoretical Chemistry
Cite this
A Study of Recombination of Hydrogen Atoms on the Surface of Solids by the Chemiluminescence Method. / Grankin, V. P.; Grankina, N. D.; Klimov, Yu V.; Tyurin, Yu I.
In: Russian Journal of Physical Chemistry A, Vol. 70, No. 10, 10.1996, p. 1729-1734.Research output: Contribution to journal › Article
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TY - JOUR
T1 - A Study of Recombination of Hydrogen Atoms on the Surface of Solids by the Chemiluminescence Method
AU - Grankin, V. P.
AU - Grankina, N. D.
AU - Klimov, Yu V.
AU - Tyurin, Yu I.
PY - 1996/10
Y1 - 1996/10
N2 - An atomic probe technique in conjunction with an atomic attenuator was used to study the recombination of hydrogen atoms on the surface of Zn2SiO4-Mn composition. The recombination of hydrogen atoms was found to occur via both the Rideal-Eley and Langmuir-Hinshelwood mechanisms. The contributions of these mechanisms to the total reaction rate were determined for various experimental conditions. The reaction rate was calculated from a nonequilibrium luminescence of the crystalline catalyst. This phenomenon is a variety of heterogeneous chemiluminescence, more specifically, radical-recombination luminescence.
AB - An atomic probe technique in conjunction with an atomic attenuator was used to study the recombination of hydrogen atoms on the surface of Zn2SiO4-Mn composition. The recombination of hydrogen atoms was found to occur via both the Rideal-Eley and Langmuir-Hinshelwood mechanisms. The contributions of these mechanisms to the total reaction rate were determined for various experimental conditions. The reaction rate was calculated from a nonequilibrium luminescence of the crystalline catalyst. This phenomenon is a variety of heterogeneous chemiluminescence, more specifically, radical-recombination luminescence.
UR - http://www.scopus.com/inward/record.url?scp=0030506136&partnerID=8YFLogxK
UR - http://www.scopus.com/inward/citedby.url?scp=0030506136&partnerID=8YFLogxK
M3 - Article
AN - SCOPUS:0030506136
VL - 70
SP - 1729
EP - 1734
JO - Russian Journal of Physical Chemistry A
JF - Russian Journal of Physical Chemistry A
SN - 0036-0244
IS - 10
ER -