A Study of Recombination of Hydrogen Atoms on the Surface of Solids by the Chemiluminescence Method

V. P. Grankin, N. D. Grankina, Yu V. Klimov, Yu I. Tyurin

Research output: Contribution to journalArticle

Abstract

An atomic probe technique in conjunction with an atomic attenuator was used to study the recombination of hydrogen atoms on the surface of Zn2SiO4-Mn composition. The recombination of hydrogen atoms was found to occur via both the Rideal-Eley and Langmuir-Hinshelwood mechanisms. The contributions of these mechanisms to the total reaction rate were determined for various experimental conditions. The reaction rate was calculated from a nonequilibrium luminescence of the crystalline catalyst. This phenomenon is a variety of heterogeneous chemiluminescence, more specifically, radical-recombination luminescence.

Original languageEnglish
Pages (from-to)1729-1734
Number of pages6
JournalRussian Journal of Physical Chemistry A
Volume70
Issue number10
Publication statusPublished - Oct 1996

Fingerprint

Chemiluminescence
chemiluminescence
Reaction rates
Luminescence
Hydrogen
hydrogen atoms
reaction kinetics
luminescence
Atoms
attenuators
Crystalline materials
catalysts
Catalysts
probes
Chemical analysis

ASJC Scopus subject areas

  • Physical and Theoretical Chemistry

Cite this

A Study of Recombination of Hydrogen Atoms on the Surface of Solids by the Chemiluminescence Method. / Grankin, V. P.; Grankina, N. D.; Klimov, Yu V.; Tyurin, Yu I.

In: Russian Journal of Physical Chemistry A, Vol. 70, No. 10, 10.1996, p. 1729-1734.

Research output: Contribution to journalArticle

@article{d173c9a997e74acbb42e60d88e4b79b0,
title = "A Study of Recombination of Hydrogen Atoms on the Surface of Solids by the Chemiluminescence Method",
abstract = "An atomic probe technique in conjunction with an atomic attenuator was used to study the recombination of hydrogen atoms on the surface of Zn2SiO4-Mn composition. The recombination of hydrogen atoms was found to occur via both the Rideal-Eley and Langmuir-Hinshelwood mechanisms. The contributions of these mechanisms to the total reaction rate were determined for various experimental conditions. The reaction rate was calculated from a nonequilibrium luminescence of the crystalline catalyst. This phenomenon is a variety of heterogeneous chemiluminescence, more specifically, radical-recombination luminescence.",
author = "Grankin, {V. P.} and Grankina, {N. D.} and Klimov, {Yu V.} and Tyurin, {Yu I.}",
year = "1996",
month = "10",
language = "English",
volume = "70",
pages = "1729--1734",
journal = "Russian Journal of Physical Chemistry A",
issn = "0036-0244",
publisher = "Maik Nauka-Interperiodica Publishing",
number = "10",

}

TY - JOUR

T1 - A Study of Recombination of Hydrogen Atoms on the Surface of Solids by the Chemiluminescence Method

AU - Grankin, V. P.

AU - Grankina, N. D.

AU - Klimov, Yu V.

AU - Tyurin, Yu I.

PY - 1996/10

Y1 - 1996/10

N2 - An atomic probe technique in conjunction with an atomic attenuator was used to study the recombination of hydrogen atoms on the surface of Zn2SiO4-Mn composition. The recombination of hydrogen atoms was found to occur via both the Rideal-Eley and Langmuir-Hinshelwood mechanisms. The contributions of these mechanisms to the total reaction rate were determined for various experimental conditions. The reaction rate was calculated from a nonequilibrium luminescence of the crystalline catalyst. This phenomenon is a variety of heterogeneous chemiluminescence, more specifically, radical-recombination luminescence.

AB - An atomic probe technique in conjunction with an atomic attenuator was used to study the recombination of hydrogen atoms on the surface of Zn2SiO4-Mn composition. The recombination of hydrogen atoms was found to occur via both the Rideal-Eley and Langmuir-Hinshelwood mechanisms. The contributions of these mechanisms to the total reaction rate were determined for various experimental conditions. The reaction rate was calculated from a nonequilibrium luminescence of the crystalline catalyst. This phenomenon is a variety of heterogeneous chemiluminescence, more specifically, radical-recombination luminescence.

UR - http://www.scopus.com/inward/record.url?scp=0030506136&partnerID=8YFLogxK

UR - http://www.scopus.com/inward/citedby.url?scp=0030506136&partnerID=8YFLogxK

M3 - Article

VL - 70

SP - 1729

EP - 1734

JO - Russian Journal of Physical Chemistry A

JF - Russian Journal of Physical Chemistry A

SN - 0036-0244

IS - 10

ER -