A simple and robust AgI/KOAc catalytic system for the carboxylative assembly of propargyl alcohols and carbon dioxide at atmospheric pressure

Ye Yuan, Yu Xie, Cheng Zeng, Dandan Song, Somboon Chaemchuen, Cheng Chen, Francis Verpoort

Research School of Chemistry & Applied Biomedical Sciences

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Abstract

A simple and robust AgI/KOAc system was developed for the cyclization of propargyl alcohols and carbon dioxide under mild conditions, and was identified to have excellent activities for numerous substrates, especially sterically hindered terminal alkynes and internal alkynes. Notably, the Ag loading involved was an unprecedentedly low level of 0.05 mol%.

Original language	English
Pages (from-to)	2933-2939
Number of pages	7
Journal	Catalysis Science and Technology
Volume	7
Issue number	14
DOIs	https://doi.org/10.1039/c7cy00696a
Publication status	Published - 1 Jan 2017

ASJC Scopus subject areas

Catalysis

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10.1039/c7cy00696a

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A simple and robust AgI/KOAc catalytic system for the carboxylative assembly of propargyl alcohols and carbon dioxide at atmospheric pressure. / Yuan, Ye; Xie, Yu; Zeng, Cheng; Song, Dandan; Chaemchuen, Somboon; Chen, Cheng; Verpoort, Francis.

In: Catalysis Science and Technology, Vol. 7, No. 14, 01.01.2017, p. 2933-2939.

Research output: Contribution to journal › Article › peer-review

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A simple and robust AgI/KOAc catalytic system for the carboxylative assembly of propargyl alcohols and carbon dioxide at atmospheric pressure

Abstract

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