A simple and robust AgI/KOAc catalytic system for the carboxylative assembly of propargyl alcohols and carbon dioxide at atmospheric pressure

Ye Yuan, Yu Xie, Cheng Zeng, Dandan Song, Somboon Chaemchuen, Cheng Chen, Francis Verpoort

Research output: Contribution to journalArticle

5 Citations (Scopus)

Abstract

A simple and robust AgI/KOAc system was developed for the cyclization of propargyl alcohols and carbon dioxide under mild conditions, and was identified to have excellent activities for numerous substrates, especially sterically hindered terminal alkynes and internal alkynes. Notably, the Ag loading involved was an unprecedentedly low level of 0.05 mol%.

Original languageEnglish
Pages (from-to)2933-2939
Number of pages7
JournalCatalysis Science and Technology
Volume7
Issue number14
DOIs
Publication statusPublished - 1 Jan 2017

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Alkynes
Cyclization
Carbon Dioxide
Atmospheric pressure
Carbon dioxide
Alcohols
Substrates
propargyl alcohol

ASJC Scopus subject areas

  • Catalysis

Cite this

A simple and robust AgI/KOAc catalytic system for the carboxylative assembly of propargyl alcohols and carbon dioxide at atmospheric pressure. / Yuan, Ye; Xie, Yu; Zeng, Cheng; Song, Dandan; Chaemchuen, Somboon; Chen, Cheng; Verpoort, Francis.

In: Catalysis Science and Technology, Vol. 7, No. 14, 01.01.2017, p. 2933-2939.

Research output: Contribution to journalArticle

Yuan, Ye ; Xie, Yu ; Zeng, Cheng ; Song, Dandan ; Chaemchuen, Somboon ; Chen, Cheng ; Verpoort, Francis. / A simple and robust AgI/KOAc catalytic system for the carboxylative assembly of propargyl alcohols and carbon dioxide at atmospheric pressure. In: Catalysis Science and Technology. 2017 ; Vol. 7, No. 14. pp. 2933-2939.
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