A simple and robust AgI/KOAc catalytic system for the carboxylative assembly of propargyl alcohols and carbon dioxide at atmospheric pressure

Ye Yuan, Yu Xie, Cheng Zeng, Dandan Song, Somboon Chaemchuen, Cheng Chen, Francis Verpoort

Research School of Chemistry & Applied Biomedical Sciences

Research output: Contribution to journal › Article

Abstract

A simple and robust AgI/KOAc system was developed for the cyclization of propargyl alcohols and carbon dioxide under mild conditions, and was identified to have excellent activities for numerous substrates, especially sterically hindered terminal alkynes and internal alkynes. Notably, the Ag loading involved was an unprecedentedly low level of 0.05 mol%.

Original language	English
Pages (from-to)	2933-2939
Number of pages	7
Journal	Catalysis Science and Technology
Volume	7
Issue number	14
DOIs	https://doi.org/10.1039/c7cy00696a
Publication status	Published - 1 Jan 2017

Fingerprint

ASJC Scopus subject areas

Catalysis

Cite this

Yuan, Y., Xie, Y., Zeng, C., Song, D., Chaemchuen, S., Chen, C., & Verpoort, F. (2017). A simple and robust AgI/KOAc catalytic system for the carboxylative assembly of propargyl alcohols and carbon dioxide at atmospheric pressure. Catalysis Science and Technology, 7(14), 2933-2939. https://doi.org/10.1039/c7cy00696a

A simple and robust AgI/KOAc catalytic system for the carboxylative assembly of propargyl alcohols and carbon dioxide at atmospheric pressure. / Yuan, Ye; Xie, Yu; Zeng, Cheng; Song, Dandan; Chaemchuen, Somboon; Chen, Cheng; Verpoort, Francis.

In: Catalysis Science and Technology, Vol. 7, No. 14, 01.01.2017, p. 2933-2939.

Research output: Contribution to journal › Article

@article{85c806bcdf884d108840a8239ca6f245,

title = "A simple and robust AgI/KOAc catalytic system for the carboxylative assembly of propargyl alcohols and carbon dioxide at atmospheric pressure",

abstract = "A simple and robust AgI/KOAc system was developed for the cyclization of propargyl alcohols and carbon dioxide under mild conditions, and was identified to have excellent activities for numerous substrates, especially sterically hindered terminal alkynes and internal alkynes. Notably, the Ag loading involved was an unprecedentedly low level of 0.05 mol%.",

author = "Ye Yuan and Yu Xie and Cheng Zeng and Dandan Song and Somboon Chaemchuen and Cheng Chen and Francis Verpoort",

year = "2017",

month = jan

day = "1",

doi = "10.1039/c7cy00696a",

language = "English",

volume = "7",

pages = "2933--2939",

journal = "Catalysis Science and Technology",

issn = "2044-4753",

publisher = "Royal Society of Chemistry",

number = "14",

}

TY - JOUR

T1 - A simple and robust AgI/KOAc catalytic system for the carboxylative assembly of propargyl alcohols and carbon dioxide at atmospheric pressure

AU - Yuan, Ye

AU - Xie, Yu

AU - Zeng, Cheng

AU - Song, Dandan

AU - Chaemchuen, Somboon

AU - Chen, Cheng

AU - Verpoort, Francis

PY - 2017/1/1

Y1 - 2017/1/1

N2 - A simple and robust AgI/KOAc system was developed for the cyclization of propargyl alcohols and carbon dioxide under mild conditions, and was identified to have excellent activities for numerous substrates, especially sterically hindered terminal alkynes and internal alkynes. Notably, the Ag loading involved was an unprecedentedly low level of 0.05 mol%.

AB - A simple and robust AgI/KOAc system was developed for the cyclization of propargyl alcohols and carbon dioxide under mild conditions, and was identified to have excellent activities for numerous substrates, especially sterically hindered terminal alkynes and internal alkynes. Notably, the Ag loading involved was an unprecedentedly low level of 0.05 mol%.

UR - http://www.scopus.com/inward/record.url?scp=85026917765&partnerID=8YFLogxK

UR - http://www.scopus.com/inward/citedby.url?scp=85026917765&partnerID=8YFLogxK

U2 - 10.1039/c7cy00696a

DO - 10.1039/c7cy00696a

M3 - Article

AN - SCOPUS:85026917765

VL - 7

SP - 2933

EP - 2939

JO - Catalysis Science and Technology

JF - Catalysis Science and Technology

SN - 2044-4753

IS - 14

ER -

Access to Document

10.1039/c7cy00696a