A simple and effective synthesis of aryl azides via arenediazonium tosylates

Abstract

Aromatic azides are formed in high yield from arenediazonium tosylates and sodium azide in water at room temperature or from aromatic amines via diazotization in the presence of p-TsOH Besides being experimentally simple, these methods do not require any metal catalysis and provide clean products without purification.

Original language	English
Article number	7106
Pages (from-to)	2706-2710
Number of pages	5
Journal	Synthesis (Germany)
Volume	45
Issue number	19
DOIs	https://doi.org/10.1055/s-0033-1339648
Publication status	Published - 9 Oct 2013

Keywords

aqueous medium
aromatic amines
diazotization
p -TsOH
sodium azide

ASJC Scopus subject areas

Catalysis
Organic Chemistry

Access to Document

10.1055/s-0033-1339648

Fingerprint Dive into the research topics of 'A simple and effective synthesis of aryl azides via arenediazonium tosylates'. Together they form a unique fingerprint.

Cite this

Kutonova, K. V., Trusova, M. E., Postnikov, P., Filimonov, V. D., & Parello, J. (2013). A simple and effective synthesis of aryl azides via arenediazonium tosylates. Synthesis (Germany), 45(19), 2706-2710. [7106]. https://doi.org/10.1055/s-0033-1339648

@article{169ea63650254a1e879b1d436772ec9d,

title = "A simple and effective synthesis of aryl azides via arenediazonium tosylates",

abstract = "Aromatic azides are formed in high yield from arenediazonium tosylates and sodium azide in water at room temperature or from aromatic amines via diazotization in the presence of p-TsOH Besides being experimentally simple, these methods do not require any metal catalysis and provide clean products without purification.",

keywords = "aqueous medium, aromatic amines, diazotization, p -TsOH, sodium azide",

author = "Kutonova, {Ksenia V.} and Trusova, {Marina E.} and Pavels Postnikov and Filimonov, {Victor D.} and Joseph Parello",

year = "2013",

month = oct,

day = "9",

doi = "10.1055/s-0033-1339648",

language = "English",

volume = "45",

pages = "2706--2710",

journal = "Synthesis",

issn = "0039-7881",

publisher = "Georg Thieme Verlag",

number = "19",

}

TY - JOUR

T1 - A simple and effective synthesis of aryl azides via arenediazonium tosylates

AU - Kutonova, Ksenia V.

AU - Trusova, Marina E.

AU - Postnikov, Pavels

AU - Filimonov, Victor D.

AU - Parello, Joseph

PY - 2013/10/9

Y1 - 2013/10/9

N2 - Aromatic azides are formed in high yield from arenediazonium tosylates and sodium azide in water at room temperature or from aromatic amines via diazotization in the presence of p-TsOH Besides being experimentally simple, these methods do not require any metal catalysis and provide clean products without purification.

AB - Aromatic azides are formed in high yield from arenediazonium tosylates and sodium azide in water at room temperature or from aromatic amines via diazotization in the presence of p-TsOH Besides being experimentally simple, these methods do not require any metal catalysis and provide clean products without purification.

KW - aqueous medium

KW - aromatic amines

KW - diazotization

KW - p -TsOH

KW - sodium azide

UR - http://www.scopus.com/inward/record.url?scp=84885004023&partnerID=8YFLogxK

UR - http://www.scopus.com/inward/citedby.url?scp=84885004023&partnerID=8YFLogxK

U2 - 10.1055/s-0033-1339648

DO - 10.1055/s-0033-1339648

M3 - Article

AN - SCOPUS:84885004023

VL - 45

SP - 2706

EP - 2710

JO - Synthesis

JF - Synthesis

SN - 0039-7881

IS - 19

M1 - 7106

ER -