A simple and effective synthesis of aryl azides via arenediazonium tosylates

Ksenia V. Kutonova, Marina E. Trusova, Pavels Postnikov, Victor D. Filimonov, Joseph Parello

Research output: Contribution to journal › Article › peer-review

Abstract

Aromatic azides are formed in high yield from arenediazonium tosylates and sodium azide in water at room temperature or from aromatic amines via diazotization in the presence of p-TsOH Besides being experimentally simple, these methods do not require any metal catalysis and provide clean products without purification.

Original language	English
Article number	7106
Pages (from-to)	2706-2710
Number of pages	5
Journal	Synthesis (Germany)
Volume	45
Issue number	19
DOIs	https://doi.org/10.1055/s-0033-1339648
Publication status	Published - 9 Oct 2013

Keywords

aqueous medium
aromatic amines
diazotization
p -TsOH
sodium azide

ASJC Scopus subject areas

Catalysis
Organic Chemistry

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10.1055/s-0033-1339648

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abstract = "Aromatic azides are formed in high yield from arenediazonium tosylates and sodium azide in water at room temperature or from aromatic amines via diazotization in the presence of p-TsOH Besides being experimentally simple, these methods do not require any metal catalysis and provide clean products without purification.",

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AU - Trusova, Marina E.

AU - Postnikov, Pavels

AU - Filimonov, Victor D.

AU - Parello, Joseph

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KW - aromatic amines

KW - diazotization

KW - p -TsOH

KW - sodium azide

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