A new look at NaBrF4: the most BrF3-rich tetrafluoridobromate(III) by mass

Sergey Ivanovich Ivlev, Roman V. Ostvald, Florian Kraus

Research output: Contribution to journalArticle

5 Citations (Scopus)

Abstract

Abstract: Sodium tetrafluoridobromate(III) was synthesized and characterized. The compound crystallizes isotypic to potassium and rubidium tetrafluoridobromate(III) in the tetragonal space group type I4/mcm with a = 5.7239(8) Å, c = 10.331(2) Å, V = 338.47(12) Å3, and Z = 4 at T = 110 K. Also, the compound was investigated by means of powder X-ray diffraction, IR and Raman spectroscopy, and theoretical calculations. Graphical abstract: [Figure not available: see fulltext.]

Original languageEnglish
Pages (from-to)1661-1668
Number of pages8
JournalMonatshefte fur Chemie
Volume147
Issue number10
DOIs
Publication statusPublished - 1 Oct 2016

Keywords

  • Ab initio calculations
  • Density functional theory
  • IR spectroscopy
  • Raman spectroscopy
  • X-ray structure determination

ASJC Scopus subject areas

  • Chemistry(all)

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