A new look at NaBrF4: the most BrF3-rich tetrafluoridobromate(III) by mass

Sergey Ivanovich Ivlev, Roman V. Ostvald, Florian Kraus

Research output: Contribution to journalArticle

3 Citations (Scopus)

Abstract

Abstract: Sodium tetrafluoridobromate(III) was synthesized and characterized. The compound crystallizes isotypic to potassium and rubidium tetrafluoridobromate(III) in the tetragonal space group type I4/mcm with a = 5.7239(8) Å, c = 10.331(2) Å, V = 338.47(12) Å3, and Z = 4 at T = 110 K. Also, the compound was investigated by means of powder X-ray diffraction, IR and Raman spectroscopy, and theoretical calculations. Graphical abstract: [Figure not available: see fulltext.]

Original languageEnglish
Pages (from-to)1661-1668
Number of pages8
JournalMonatshefte fur Chemie
Volume147
Issue number10
DOIs
Publication statusPublished - 1 Oct 2016

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Rubidium
X ray powder diffraction
Raman spectroscopy
Infrared spectroscopy
Potassium
Sodium

Keywords

  • Ab initio calculations
  • Density functional theory
  • IR spectroscopy
  • Raman spectroscopy
  • X-ray structure determination

ASJC Scopus subject areas

  • Chemistry(all)

Cite this

A new look at NaBrF4 : the most BrF3-rich tetrafluoridobromate(III) by mass. / Ivlev, Sergey Ivanovich; Ostvald, Roman V.; Kraus, Florian.

In: Monatshefte fur Chemie, Vol. 147, No. 10, 01.10.2016, p. 1661-1668.

Research output: Contribution to journalArticle

Ivlev, Sergey Ivanovich ; Ostvald, Roman V. ; Kraus, Florian. / A new look at NaBrF4 : the most BrF3-rich tetrafluoridobromate(III) by mass. In: Monatshefte fur Chemie. 2016 ; Vol. 147, No. 10. pp. 1661-1668.
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