Abstract
Simple hydroxyamino acid derivatives act as chiral ligands in osmium-catalyzed dihydroxylation and aminohydroxylation of olefins (see scheme). These are the first examples of asymmetric osmium-catalyzed processes proceeding in the second catalytic cycle with resident ligands on the metal center.
Original language | English |
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Pages (from-to) | 472-475 |
Number of pages | 4 |
Journal | Angewandte Chemie - International Edition |
Volume | 41 |
Issue number | 3 |
DOIs | |
Publication status | Published - 1 Feb 2002 |
Externally published | Yes |
Keywords
- Alkenes
- Aminohydroxylation
- Dihydroxylation
- Homogeneous catalysis
- Osmium
ASJC Scopus subject areas
- Chemistry(all)