A new approach to osmium-catalyzed asymmetric dihydroxylation and aminohydroxylation of olefins

Abstract

Simple hydroxyamino acid derivatives act as chiral ligands in osmium-catalyzed dihydroxylation and aminohydroxylation of olefins (see scheme). These are the first examples of asymmetric osmium-catalyzed processes proceeding in the second catalytic cycle with resident ligands on the metal center.

Original language	English
Pages (from-to)	472-475
Number of pages	4
Journal	Angewandte Chemie - International Edition
Volume	41
Issue number	3
DOIs	https://doi.org/10.1002/1521-3773(20020201)41:3<472::AID-ANIE472>3.0.CO;2-7
Publication status	Published - 1 Feb 2002
Externally published	Yes

Keywords

Alkenes
Aminohydroxylation
Dihydroxylation
Homogeneous catalysis
Osmium

ASJC Scopus subject areas

Chemistry(all)

Access to Document

10.1002/1521-3773(20020201)41:3<472::AID-ANIE472>3.0.CO;2-7

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abstract = "Simple hydroxyamino acid derivatives act as chiral ligands in osmium-catalyzed dihydroxylation and aminohydroxylation of olefins (see scheme). These are the first examples of asymmetric osmium-catalyzed processes proceeding in the second catalytic cycle with resident ligands on the metal center.",

keywords = "Alkenes, Aminohydroxylation, Dihydroxylation, Homogeneous catalysis, Osmium",

author = "Andersson, {Malin A.} and Robert Epple and Fokin, {Valery V.} and Sharpless, {K. Barry}",

year = "2002",

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T1 - A new approach to osmium-catalyzed asymmetric dihydroxylation and aminohydroxylation of olefins

AU - Andersson, Malin A.

AU - Epple, Robert

AU - Fokin, Valery V.

AU - Sharpless, K. Barry

PY - 2002/2/1

Y1 - 2002/2/1

N2 - Simple hydroxyamino acid derivatives act as chiral ligands in osmium-catalyzed dihydroxylation and aminohydroxylation of olefins (see scheme). These are the first examples of asymmetric osmium-catalyzed processes proceeding in the second catalytic cycle with resident ligands on the metal center.

AB - Simple hydroxyamino acid derivatives act as chiral ligands in osmium-catalyzed dihydroxylation and aminohydroxylation of olefins (see scheme). These are the first examples of asymmetric osmium-catalyzed processes proceeding in the second catalytic cycle with resident ligands on the metal center.

KW - Alkenes

KW - Aminohydroxylation

KW - Dihydroxylation

KW - Homogeneous catalysis

KW - Osmium

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