A new approach to osmium-catalyzed asymmetric dihydroxylation and aminohydroxylation of olefins

Abstract

Simple hydroxyamino acid derivatives act as chiral ligands in osmium-catalyzed dihydroxylation and aminohydroxylation of olefins (see scheme). These are the first examples of asymmetric osmium-catalyzed processes proceeding in the second catalytic cycle with resident ligands on the metal center.

Original language	English
Pages (from-to)	472-475
Number of pages	4
Journal	Angewandte Chemie - International Edition
Volume	41
Issue number	3
DOIs	https://doi.org/10.1002/1521-3773(20020201)41:3<472::AID-ANIE472>3.0.CO;2-7
Publication status	Published - 1 Feb 2002
Externally published	Yes

Keywords

Alkenes
Aminohydroxylation
Dihydroxylation
Homogeneous catalysis
Osmium

ASJC Scopus subject areas

Chemistry(all)

Access to Document

10.1002/1521-3773(20020201)41:3<472::AID-ANIE472>3.0.CO;2-7

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Andersson, M. A., Epple, R., Fokin, V. V., & Sharpless, K. B. (2002). A new approach to osmium-catalyzed asymmetric dihydroxylation and aminohydroxylation of olefins. Angewandte Chemie - International Edition, 41(3), 472-475. https://doi.org/10.1002/1521-3773(20020201)41:3<472::AID-ANIE472>3.0.CO;2-7

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AU - Sharpless, K. Barry

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