Abstract
Simple hydroxyamino acid derivatives act as chiral ligands in osmium-catalyzed dihydroxylation and aminohydroxylation of olefins (see scheme). These are the first examples of asymmetric osmium-catalyzed processes proceeding in the second catalytic cycle with resident ligands on the metal center.
| Original language | English |
|---|---|
| Pages (from-to) | 472-475 |
| Number of pages | 4 |
| Journal | Angewandte Chemie - International Edition |
| Volume | 41 |
| Issue number | 3 |
| DOIs | |
| Publication status | Published - 1 Feb 2002 |
| Externally published | Yes |
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Keywords
- Alkenes
- Aminohydroxylation
- Dihydroxylation
- Homogeneous catalysis
- Osmium
ASJC Scopus subject areas
- Chemistry(all)
Cite this
A new approach to osmium-catalyzed asymmetric dihydroxylation and aminohydroxylation of olefins. / Andersson, Malin A.; Epple, Robert; Fokin, Valery V.; Sharpless, K. Barry.
In: Angewandte Chemie - International Edition, Vol. 41, No. 3, 01.02.2002, p. 472-475.Research output: Contribution to journal › Article
}
TY - JOUR
T1 - A new approach to osmium-catalyzed asymmetric dihydroxylation and aminohydroxylation of olefins
AU - Andersson, Malin A.
AU - Epple, Robert
AU - Fokin, Valery V.
AU - Sharpless, K. Barry
PY - 2002/2/1
Y1 - 2002/2/1
N2 - Simple hydroxyamino acid derivatives act as chiral ligands in osmium-catalyzed dihydroxylation and aminohydroxylation of olefins (see scheme). These are the first examples of asymmetric osmium-catalyzed processes proceeding in the second catalytic cycle with resident ligands on the metal center.
AB - Simple hydroxyamino acid derivatives act as chiral ligands in osmium-catalyzed dihydroxylation and aminohydroxylation of olefins (see scheme). These are the first examples of asymmetric osmium-catalyzed processes proceeding in the second catalytic cycle with resident ligands on the metal center.
KW - Alkenes
KW - Aminohydroxylation
KW - Dihydroxylation
KW - Homogeneous catalysis
KW - Osmium
UR - http://www.scopus.com/inward/record.url?scp=0036462501&partnerID=8YFLogxK
UR - http://www.scopus.com/inward/citedby.url?scp=0036462501&partnerID=8YFLogxK
U2 - 10.1002/1521-3773(20020201)41:3<472::AID-ANIE472>3.0.CO;2-7
DO - 10.1002/1521-3773(20020201)41:3<472::AID-ANIE472>3.0.CO;2-7
M3 - Article
VL - 41
SP - 472
EP - 475
JO - Angewandte Chemie - International Edition
JF - Angewandte Chemie - International Edition
SN - 1433-7851
IS - 3
ER -