Simple hydroxyamino acid derivatives act as chiral ligands in osmium-catalyzed dihydroxylation and aminohydroxylation of olefins (see scheme). These are the first examples of asymmetric osmium-catalyzed processes proceeding in the second catalytic cycle with resident ligands on the metal center.
|Number of pages||4|
|Journal||Angewandte Chemie - International Edition|
|Publication status||Published - 1 Feb 2002|
- Homogeneous catalysis
ASJC Scopus subject areas