Abstract
"Chemical Equation Presented" [Bis(trifiuoroacetoxy)iodo] perfiuoroalkanes CnF2n+1I(OC-OCF3)2 (n = 4, 6, 8, 10, 12) can be conveniently prepared by the oxidation of the corresponding perfluoroalkyl iodides with Oxone in trifluoroacetic acid at room temperature and subsequently converted to the stable [hydroxy(tosyloxy)-iodo] perfluoroalkanes, CnF2n+1I(OH)OTs, by treatment with p-toluenesulfonic acid. This general and convenient procedure has been further extended to the synthesis of various [bis(trifluoroacetoxy)iodo]arenes, ArI(OCOCF3)2.
| Original language | English |
|---|---|
| Pages (from-to) | 2119-2122 |
| Number of pages | 4 |
| Journal | Journal of Organic Chemistry |
| Volume | 75 |
| Issue number | 6 |
| DOIs | |
| Publication status | Published - 19 Mar 2010 |
ASJC Scopus subject areas
- Organic Chemistry
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Cite this
Zagulyaeva, A. A., Yusubov, M. S., & Zhdankin, V. V. (2010). A general and convenient preparation of [Bis(trifluoroacetoxy)iodo] perfluoroalkanes and [Bis(trifluoroacetoxy)iodo] arenes by oxidation of organic iodides using Oxone and trifluoroacetic acid. Journal of Organic Chemistry, 75(6), 2119-2122. https://doi.org/10.1021/jo902733f