A colorimetric sensor based on a polymethacrylate matrix with immobilized 1-(2-pyridylazo)-2-naphthol for the determination of cobalt

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Abstract

A colorimetric sensor is proposed for the determination of cobalt. It is prepared by immobilizing 1-(2-pyridylazo)-2-naphthol (PAN) in an optically transparent polymethacrylate matrix. The conditions for determining cobalt by the proposed colorimetric sensor are found in the study of the complexation of cobalt with a PAN-modified polymethacrylate matrix. The determination is based on the interaction of the sensor with a cobalt solution at pH 4 for 5 min, followed by the measurement of absorbance at 620 nm. The sensor ensures the determination of 0.05–0.50 mg/L of cobalt with the detection limit 0.03 mg/L. It is demonstrated that the sensor can be used for the determination of cobalt in the Cyanocobalamin medical preparation and potable water.

Original languageEnglish
Pages (from-to)1475-1479
Number of pages5
JournalJournal of Analytical Chemistry
Volume70
Issue number12
DOIs
Publication statusPublished - 1 Dec 2015

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Cobalt
Sensors
Vitamin B 12
Complexation
Drinking Water
1-(2-pyridylazo)-2-naphthol
polymethacrylic acid

Keywords

  • cobalt
  • colorimetric sensor
  • immobilized reagent
  • polymethacrylate matrix
  • solid-phase spectrophotometry

ASJC Scopus subject areas

  • Analytical Chemistry

Cite this

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title = "A colorimetric sensor based on a polymethacrylate matrix with immobilized 1-(2-pyridylazo)-2-naphthol for the determination of cobalt",
abstract = "A colorimetric sensor is proposed for the determination of cobalt. It is prepared by immobilizing 1-(2-pyridylazo)-2-naphthol (PAN) in an optically transparent polymethacrylate matrix. The conditions for determining cobalt by the proposed colorimetric sensor are found in the study of the complexation of cobalt with a PAN-modified polymethacrylate matrix. The determination is based on the interaction of the sensor with a cobalt solution at pH 4 for 5 min, followed by the measurement of absorbance at 620 nm. The sensor ensures the determination of 0.05–0.50 mg/L of cobalt with the detection limit 0.03 mg/L. It is demonstrated that the sensor can be used for the determination of cobalt in the Cyanocobalamin medical preparation and potable water.",
keywords = "cobalt, colorimetric sensor, immobilized reagent, polymethacrylate matrix, solid-phase spectrophotometry",
author = "Gavrilenko, {Nataliya Airatovna} and Saranchina, {N. V.} and Gavrilenko, {M. A.}",
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AU - Saranchina, N. V.

AU - Gavrilenko, M. A.

PY - 2015/12/1

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N2 - A colorimetric sensor is proposed for the determination of cobalt. It is prepared by immobilizing 1-(2-pyridylazo)-2-naphthol (PAN) in an optically transparent polymethacrylate matrix. The conditions for determining cobalt by the proposed colorimetric sensor are found in the study of the complexation of cobalt with a PAN-modified polymethacrylate matrix. The determination is based on the interaction of the sensor with a cobalt solution at pH 4 for 5 min, followed by the measurement of absorbance at 620 nm. The sensor ensures the determination of 0.05–0.50 mg/L of cobalt with the detection limit 0.03 mg/L. It is demonstrated that the sensor can be used for the determination of cobalt in the Cyanocobalamin medical preparation and potable water.

AB - A colorimetric sensor is proposed for the determination of cobalt. It is prepared by immobilizing 1-(2-pyridylazo)-2-naphthol (PAN) in an optically transparent polymethacrylate matrix. The conditions for determining cobalt by the proposed colorimetric sensor are found in the study of the complexation of cobalt with a PAN-modified polymethacrylate matrix. The determination is based on the interaction of the sensor with a cobalt solution at pH 4 for 5 min, followed by the measurement of absorbance at 620 nm. The sensor ensures the determination of 0.05–0.50 mg/L of cobalt with the detection limit 0.03 mg/L. It is demonstrated that the sensor can be used for the determination of cobalt in the Cyanocobalamin medical preparation and potable water.

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KW - solid-phase spectrophotometry

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