Abstract
4,4′-Bis(dichloroiodo)biphenyl and 3-(dichloroiodo)benzoic acid are convenient recyclable hypervalent iodine reagents for vicinal chloromethoxylation or iodomethoxylation of unsaturated compounds. The reactivity of these reagents in the reaction of vicinal halomethoxylation is generally similar to dichloroiodobenzene and the advantage of their use is that the reduced forms of these reagents can be easily separated from the reaction mixture and reused for the regeneration of the reagents.
| Original language | English |
|---|---|
| Pages (from-to) | 2289-2292 |
| Number of pages | 4 |
| Journal | Synthesis |
| Issue number | 14 |
| DOIs | |
| Publication status | Published - 1 Oct 2004 |
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Keywords
- Alkenes
- Electrophilic additions
- Halogens
- Hypervalent iodine
- Oxidations
ASJC Scopus subject areas
- Organic Chemistry
Cite this
4,4′-Bis(dichloroiodo)biphenyl and 3-(dichloroiodo)benzoic acid : New recyclable hypervalent iodine reagents for vicinal halomethoxylation of unsaturated compounds. / Yusubov, Mehman S.; Drygunova, Larisa Alexandrovna; Zhdankin, Viktor Vladimirovich.
In: Synthesis, No. 14, 01.10.2004, p. 2289-2292.Research output: Contribution to journal › Article
}
TY - JOUR
T1 - 4,4′-Bis(dichloroiodo)biphenyl and 3-(dichloroiodo)benzoic acid
T2 - New recyclable hypervalent iodine reagents for vicinal halomethoxylation of unsaturated compounds
AU - Yusubov, Mehman S.
AU - Drygunova, Larisa Alexandrovna
AU - Zhdankin, Viktor Vladimirovich
PY - 2004/10/1
Y1 - 2004/10/1
N2 - 4,4′-Bis(dichloroiodo)biphenyl and 3-(dichloroiodo)benzoic acid are convenient recyclable hypervalent iodine reagents for vicinal chloromethoxylation or iodomethoxylation of unsaturated compounds. The reactivity of these reagents in the reaction of vicinal halomethoxylation is generally similar to dichloroiodobenzene and the advantage of their use is that the reduced forms of these reagents can be easily separated from the reaction mixture and reused for the regeneration of the reagents.
AB - 4,4′-Bis(dichloroiodo)biphenyl and 3-(dichloroiodo)benzoic acid are convenient recyclable hypervalent iodine reagents for vicinal chloromethoxylation or iodomethoxylation of unsaturated compounds. The reactivity of these reagents in the reaction of vicinal halomethoxylation is generally similar to dichloroiodobenzene and the advantage of their use is that the reduced forms of these reagents can be easily separated from the reaction mixture and reused for the regeneration of the reagents.
KW - Alkenes
KW - Electrophilic additions
KW - Halogens
KW - Hypervalent iodine
KW - Oxidations
UR - http://www.scopus.com/inward/record.url?scp=5644275250&partnerID=8YFLogxK
UR - http://www.scopus.com/inward/citedby.url?scp=5644275250&partnerID=8YFLogxK
U2 - 10.1055/s-2004-831175
DO - 10.1055/s-2004-831175
M3 - Article
AN - SCOPUS:5644275250
SP - 2289
EP - 2292
JO - Synthesis
JF - Synthesis
SN - 0039-7881
IS - 14
ER -