3D derived N-doped carbon matrix from 2D ZIF-L as an enhanced stable catalyst for chemical fixation

Matteo Ciprian, Karla Hernandez Ruiz, Meruyert Kassymova, Tingting Wang, Serge Zhuiykov, Somboon Chaemchuen, Rong Tu, Francis Verpoort

Research output: Contribution to journalArticle

2 Citations (Scopus)

Abstract

3D metal N-doped carbon frameworks (M-NCFs) are produced from the direct pyrolysis of 2D zeolitic imidazolate frameworks (ZIF-L Zn and Co) in a reducing atmosphere. The effects of the thermal treatment were studied in order to achieve the desired catalyst. The results show that metal nanoparticles and N-doping species present in the carbon matrix have a direct influence on the catalytic performance. Zn/NCF-1000 displayed quantitative conversion and selectivity towards the chemical fixation of carbon dioxide through the cycloaddition with epoxides. Furthermore, the magnetic property of the newly synthesized Co/NCF-600 was used to demonstrate its superior stability and recyclability, retaining the same catalytic activity for more than 10 cycles.

Original languageEnglish
Pages (from-to)80-88
Number of pages9
JournalMicroporous and Mesoporous Materials
Volume285
DOIs
Publication statusPublished - 1 Sep 2019

Fingerprint

Carbon
catalysts
Catalysts
Cycloaddition
epoxy compounds
Metal nanoparticles
carbon
Epoxy Compounds
cycloaddition
matrices
retaining
Carbon Dioxide
metals
pyrolysis
catalytic activity
carbon dioxide
Catalyst activity
Magnetic properties
Carbon dioxide
Pyrolysis

Keywords

  • Carbonates
  • CO fixation
  • Heterogeneous catalyst
  • Pyrolysis
  • ZIF-L

ASJC Scopus subject areas

  • Chemistry(all)
  • Materials Science(all)
  • Condensed Matter Physics
  • Mechanics of Materials

Cite this

3D derived N-doped carbon matrix from 2D ZIF-L as an enhanced stable catalyst for chemical fixation. / Ciprian, Matteo; Ruiz, Karla Hernandez; Kassymova, Meruyert; Wang, Tingting; Zhuiykov, Serge; Chaemchuen, Somboon; Tu, Rong; Verpoort, Francis.

In: Microporous and Mesoporous Materials, Vol. 285, 01.09.2019, p. 80-88.

Research output: Contribution to journalArticle

Ciprian, Matteo ; Ruiz, Karla Hernandez ; Kassymova, Meruyert ; Wang, Tingting ; Zhuiykov, Serge ; Chaemchuen, Somboon ; Tu, Rong ; Verpoort, Francis. / 3D derived N-doped carbon matrix from 2D ZIF-L as an enhanced stable catalyst for chemical fixation. In: Microporous and Mesoporous Materials. 2019 ; Vol. 285. pp. 80-88.
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AU - Ciprian, Matteo

AU - Ruiz, Karla Hernandez

AU - Kassymova, Meruyert

AU - Wang, Tingting

AU - Zhuiykov, Serge

AU - Chaemchuen, Somboon

AU - Tu, Rong

AU - Verpoort, Francis

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