2-Iodoxybenzoic acid organosulfonates: preparation, X-ray structure and reactivity of new, powerful hypervalent iodine(v) oxidants

Preparation, X-ray structure and reactivity of new, powerful hypervalent iodine(v) oxidants

Mekhman S. Yusubov, Dmitrii Yu Svitich, Akira Yoshimura, Victor N. Nemykin, Viktor Vladimirovich Zhdankin

Research output: Contribution to journalArticle

11 Citations (Scopus)

Abstract

New powerful hypervalent iodine(v) oxidants, tosylate and mesylate derivatives of 2-iodoxybenzoic acid (IBX), were prepared by the reaction of IBX with the corresponding sulfonic acids. Single crystal X-ray crystallography of the diacetate derivative of IBX-tosylate revealed an unusual heptacoordinated iodine geometry without any significant intermolecular secondary interactions.

Original languageEnglish
Pages (from-to)11269-11271
Number of pages3
JournalChemical Communications
Volume49
Issue number96
DOIs
Publication statusPublished - 14 Dec 2013

Fingerprint

Iodine
Oxidants
Derivatives
X rays
Mesylates
Sulfonic Acids
Acids
X ray crystallography
Single crystals
Geometry
2-iodoxybenzoic acid

ASJC Scopus subject areas

  • Catalysis
  • Electronic, Optical and Magnetic Materials
  • Ceramics and Composites
  • Chemistry(all)
  • Surfaces, Coatings and Films
  • Metals and Alloys
  • Materials Chemistry

Cite this

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title = "2-Iodoxybenzoic acid organosulfonates: preparation, X-ray structure and reactivity of new, powerful hypervalent iodine(v) oxidants: Preparation, X-ray structure and reactivity of new, powerful hypervalent iodine(v) oxidants",
abstract = "New powerful hypervalent iodine(v) oxidants, tosylate and mesylate derivatives of 2-iodoxybenzoic acid (IBX), were prepared by the reaction of IBX with the corresponding sulfonic acids. Single crystal X-ray crystallography of the diacetate derivative of IBX-tosylate revealed an unusual heptacoordinated iodine geometry without any significant intermolecular secondary interactions.",
author = "Yusubov, {Mekhman S.} and Svitich, {Dmitrii Yu} and Akira Yoshimura and Nemykin, {Victor N.} and Zhdankin, {Viktor Vladimirovich}",
year = "2013",
month = "12",
day = "14",
doi = "10.1039/c3cc47090c",
language = "English",
volume = "49",
pages = "11269--11271",
journal = "Chemical Communications",
issn = "1359-7345",
publisher = "Royal Society of Chemistry",
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TY - JOUR

T1 - 2-Iodoxybenzoic acid organosulfonates: preparation, X-ray structure and reactivity of new, powerful hypervalent iodine(v) oxidants

T2 - Preparation, X-ray structure and reactivity of new, powerful hypervalent iodine(v) oxidants

AU - Yusubov, Mekhman S.

AU - Svitich, Dmitrii Yu

AU - Yoshimura, Akira

AU - Nemykin, Victor N.

AU - Zhdankin, Viktor Vladimirovich

PY - 2013/12/14

Y1 - 2013/12/14

N2 - New powerful hypervalent iodine(v) oxidants, tosylate and mesylate derivatives of 2-iodoxybenzoic acid (IBX), were prepared by the reaction of IBX with the corresponding sulfonic acids. Single crystal X-ray crystallography of the diacetate derivative of IBX-tosylate revealed an unusual heptacoordinated iodine geometry without any significant intermolecular secondary interactions.

AB - New powerful hypervalent iodine(v) oxidants, tosylate and mesylate derivatives of 2-iodoxybenzoic acid (IBX), were prepared by the reaction of IBX with the corresponding sulfonic acids. Single crystal X-ray crystallography of the diacetate derivative of IBX-tosylate revealed an unusual heptacoordinated iodine geometry without any significant intermolecular secondary interactions.

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U2 - 10.1039/c3cc47090c

DO - 10.1039/c3cc47090c

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JF - Chemical Communications

SN - 1359-7345

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