2-Iodoxybenzoic acid ditriflate: The most powerful hypervalent iodine(v) oxidant

Research output: Contribution to journalArticle

Abstract

A ditriflate derivative of 2-iodoxybenzoic acid (IBX) was prepared by the reaction of IBX with trifluoromethanesulfonic acid and characterized by single crystal X-ray crystallography. IBX-ditriflate is the most powerful oxidant in a series of structurally similar IBX derivatives which is best illustrated by its ability to readily oxidize hydrocarbons and the oxidation resistant polyfluoroalcohols.

Original languageEnglish
Pages (from-to)7760-7763
Number of pages4
JournalChemical Communications
Volume55
Issue number54
DOIs
Publication statusPublished - 1 Jan 2019

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Iodine
Oxidants
Derivatives
Acids
X ray crystallography
Hydrocarbons
Single crystals
Oxidation
2-iodoxybenzoic acid
trifluoromethanesulfonic acid

ASJC Scopus subject areas

  • Catalysis
  • Electronic, Optical and Magnetic Materials
  • Ceramics and Composites
  • Chemistry(all)
  • Surfaces, Coatings and Films
  • Metals and Alloys
  • Materials Chemistry

Cite this

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abstract = "A ditriflate derivative of 2-iodoxybenzoic acid (IBX) was prepared by the reaction of IBX with trifluoromethanesulfonic acid and characterized by single crystal X-ray crystallography. IBX-ditriflate is the most powerful oxidant in a series of structurally similar IBX derivatives which is best illustrated by its ability to readily oxidize hydrocarbons and the oxidation resistant polyfluoroalcohols.",
author = "Yusubov, {Mekhman S.} and Soldatova, {Natalia S.} and Postnikov, {Pavel S.} and Valiev, {Rashid R.} and Akira Yoshimura and Thomas Wirth and Nemykin, {Victor N.} and Zhdankin, {Viktor V.}",
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publisher = "Royal Society of Chemistry",
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TY - JOUR

T1 - 2-Iodoxybenzoic acid ditriflate

T2 - The most powerful hypervalent iodine(v) oxidant

AU - Yusubov, Mekhman S.

AU - Soldatova, Natalia S.

AU - Postnikov, Pavel S.

AU - Valiev, Rashid R.

AU - Yoshimura, Akira

AU - Wirth, Thomas

AU - Nemykin, Victor N.

AU - Zhdankin, Viktor V.

PY - 2019/1/1

Y1 - 2019/1/1

N2 - A ditriflate derivative of 2-iodoxybenzoic acid (IBX) was prepared by the reaction of IBX with trifluoromethanesulfonic acid and characterized by single crystal X-ray crystallography. IBX-ditriflate is the most powerful oxidant in a series of structurally similar IBX derivatives which is best illustrated by its ability to readily oxidize hydrocarbons and the oxidation resistant polyfluoroalcohols.

AB - A ditriflate derivative of 2-iodoxybenzoic acid (IBX) was prepared by the reaction of IBX with trifluoromethanesulfonic acid and characterized by single crystal X-ray crystallography. IBX-ditriflate is the most powerful oxidant in a series of structurally similar IBX derivatives which is best illustrated by its ability to readily oxidize hydrocarbons and the oxidation resistant polyfluoroalcohols.

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U2 - 10.1039/c9cc04203b

DO - 10.1039/c9cc04203b

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JF - Chemical Communications

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