Abstract
A ditriflate derivative of 2-iodoxybenzoic acid (IBX) was prepared by the reaction of IBX with trifluoromethanesulfonic acid and characterized by single crystal X-ray crystallography. IBX-ditriflate is the most powerful oxidant in a series of structurally similar IBX derivatives which is best illustrated by its ability to readily oxidize hydrocarbons and the oxidation resistant polyfluoroalcohols.
| Original language | English |
|---|---|
| Pages (from-to) | 7760-7763 |
| Number of pages | 4 |
| Journal | Chemical Communications |
| Volume | 55 |
| Issue number | 54 |
| DOIs | |
| Publication status | Published - 1 Jan 2019 |
ASJC Scopus subject areas
- Catalysis
- Electronic, Optical and Magnetic Materials
- Ceramics and Composites
- Chemistry(all)
- Surfaces, Coatings and Films
- Metals and Alloys
- Materials Chemistry
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Cite this
Yusubov, M. S., Soldatova, N. S., Postnikov, P. S., Valiev, R. R., Yoshimura, A., Wirth, T., Nemykin, V. N., & Zhdankin, V. V. (2019). 2-Iodoxybenzoic acid ditriflate: The most powerful hypervalent iodine(v) oxidant. Chemical Communications, 55(54), 7760-7763. https://doi.org/10.1039/c9cc04203b