Abstract
A ditriflate derivative of 2-iodoxybenzoic acid (IBX) was prepared by the reaction of IBX with trifluoromethanesulfonic acid and characterized by single crystal X-ray crystallography. IBX-ditriflate is the most powerful oxidant in a series of structurally similar IBX derivatives which is best illustrated by its ability to readily oxidize hydrocarbons and the oxidation resistant polyfluoroalcohols.
| Original language | English |
|---|---|
| Pages (from-to) | 7760-7763 |
| Number of pages | 4 |
| Journal | Chemical Communications |
| Volume | 55 |
| Issue number | 54 |
| DOIs | |
| Publication status | Published - 1 Jan 2019 |
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ASJC Scopus subject areas
- Catalysis
- Electronic, Optical and Magnetic Materials
- Ceramics and Composites
- Chemistry(all)
- Surfaces, Coatings and Films
- Metals and Alloys
- Materials Chemistry
Cite this
2-Iodoxybenzoic acid ditriflate : The most powerful hypervalent iodine(v) oxidant. / Yusubov, Mekhman S.; Soldatova, Natalia S.; Postnikov, Pavel S.; Valiev, Rashid R.; Yoshimura, Akira; Wirth, Thomas; Nemykin, Victor N.; Zhdankin, Viktor V.
In: Chemical Communications, Vol. 55, No. 54, 01.01.2019, p. 7760-7763.Research output: Contribution to journal › Article
}
TY - JOUR
T1 - 2-Iodoxybenzoic acid ditriflate
T2 - The most powerful hypervalent iodine(v) oxidant
AU - Yusubov, Mekhman S.
AU - Soldatova, Natalia S.
AU - Postnikov, Pavel S.
AU - Valiev, Rashid R.
AU - Yoshimura, Akira
AU - Wirth, Thomas
AU - Nemykin, Victor N.
AU - Zhdankin, Viktor V.
PY - 2019/1/1
Y1 - 2019/1/1
N2 - A ditriflate derivative of 2-iodoxybenzoic acid (IBX) was prepared by the reaction of IBX with trifluoromethanesulfonic acid and characterized by single crystal X-ray crystallography. IBX-ditriflate is the most powerful oxidant in a series of structurally similar IBX derivatives which is best illustrated by its ability to readily oxidize hydrocarbons and the oxidation resistant polyfluoroalcohols.
AB - A ditriflate derivative of 2-iodoxybenzoic acid (IBX) was prepared by the reaction of IBX with trifluoromethanesulfonic acid and characterized by single crystal X-ray crystallography. IBX-ditriflate is the most powerful oxidant in a series of structurally similar IBX derivatives which is best illustrated by its ability to readily oxidize hydrocarbons and the oxidation resistant polyfluoroalcohols.
UR - http://www.scopus.com/inward/record.url?scp=85068510974&partnerID=8YFLogxK
UR - http://www.scopus.com/inward/citedby.url?scp=85068510974&partnerID=8YFLogxK
U2 - 10.1039/c9cc04203b
DO - 10.1039/c9cc04203b
M3 - Article
C2 - 31209449
AN - SCOPUS:85068510974
VL - 55
SP - 7760
EP - 7763
JO - Chemical Communications
JF - Chemical Communications
SN - 1359-7345
IS - 54
ER -