2-Iodoxybenzoic acid ditriflate: The most powerful hypervalent iodine(v) oxidant

Mekhman S. Yusubov, Natalia S. Soldatova, Pavel S. Postnikov, Rashid R. Valiev, Akira Yoshimura, Thomas Wirth, Victor N. Nemykin, Viktor V. Zhdankin

Research School of Chemistry & Applied Biomedical Sciences

Research output: Contribution to journal › Article

2 Citations (Scopus)

Abstract

A ditriflate derivative of 2-iodoxybenzoic acid (IBX) was prepared by the reaction of IBX with trifluoromethanesulfonic acid and characterized by single crystal X-ray crystallography. IBX-ditriflate is the most powerful oxidant in a series of structurally similar IBX derivatives which is best illustrated by its ability to readily oxidize hydrocarbons and the oxidation resistant polyfluoroalcohols.

Original language	English
Pages (from-to)	7760-7763
Number of pages	4
Journal	Chemical Communications
Volume	55
Issue number	54
DOIs	https://doi.org/10.1039/c9cc04203b
Publication status	Published - 1 Jan 2019

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ASJC Scopus subject areas

Catalysis
Electronic, Optical and Magnetic Materials
Ceramics and Composites
Chemistry(all)
Surfaces, Coatings and Films
Metals and Alloys
Materials Chemistry

Cite this

Yusubov, M. S., Soldatova, N. S., Postnikov, P. S., Valiev, R. R., Yoshimura, A., Wirth, T., Nemykin, V. N., & Zhdankin, V. V. (2019). 2-Iodoxybenzoic acid ditriflate: The most powerful hypervalent iodine(v) oxidant. Chemical Communications, 55(54), 7760-7763. https://doi.org/10.1039/c9cc04203b

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AU - Soldatova, Natalia S.

AU - Postnikov, Pavel S.

AU - Valiev, Rashid R.

AU - Yoshimura, Akira

AU - Wirth, Thomas

AU - Nemykin, Victor N.

AU - Zhdankin, Viktor V.

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Access to Document

10.1039/c9cc04203b