2-Iodoxybenzoic acid ditriflate: The most powerful hypervalent iodine(v) oxidant

Mekhman S. Yusubov, Natalia S. Soldatova, Pavel S. Postnikov, Rashid R. Valiev, Akira Yoshimura, Thomas Wirth, Victor N. Nemykin, Viktor V. Zhdankin

Research output: Contribution to journalArticlepeer-review

7 Citations (Scopus)

Abstract

A ditriflate derivative of 2-iodoxybenzoic acid (IBX) was prepared by the reaction of IBX with trifluoromethanesulfonic acid and characterized by single crystal X-ray crystallography. IBX-ditriflate is the most powerful oxidant in a series of structurally similar IBX derivatives which is best illustrated by its ability to readily oxidize hydrocarbons and the oxidation resistant polyfluoroalcohols.

Original languageEnglish
Pages (from-to)7760-7763
Number of pages4
JournalChemical Communications
Volume55
Issue number54
DOIs
Publication statusPublished - 1 Jan 2019

ASJC Scopus subject areas

  • Catalysis
  • Electronic, Optical and Magnetic Materials
  • Ceramics and Composites
  • Chemistry(all)
  • Surfaces, Coatings and Films
  • Metals and Alloys
  • Materials Chemistry

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