2-(2-Pyridylamino)pyridinium Salts of closo-Hydridoborate Anions BnHn 2- (n = 6,10, or 12)

Abstract

2-(2-Pyridylamino)pyridinium salts (Hpy₂NH)₂B₁₂H₁₂, (Hpy₂NH)₂B₁₀H₁₀ - 2H₂O, and (Hpy₂NH)₂B₆H₆ - 2H₂O were synthesized and then characterized by IR spectroscopy. On the basis of IR spectroscopic data, the behavior of imino groups of 2-(2-pyridylamino)pyridinium in the title compounds is considered. X-ray structural analysis of the (Hpy₂NH)₂B₁₀H₁₀ - 2H₂O is performed. The crystals are triclinic, a = 9.649(2) Å, b = 10.020(1) Å, c = 14.924 Å, α = 93.23(2)°, β = 98.44(2)°, γ = 106.45(1)°, V = 1361.6(6) Å³, space group P 1̌ (no. 2), Z = 2.

Original language	English
Pages (from-to)	1856-1861
Number of pages	6
Journal	Russian Journal of Inorganic Chemistry
Volume	41
Issue number	12
Publication status	Published - 1996
Externally published	Yes

ASJC Scopus subject areas

Materials Science (miscellaneous)
Physical and Theoretical Chemistry
Inorganic Chemistry

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@article{36ce7379fae54d2baa4c5adb204c51e3,

title = "2-(2-Pyridylamino)pyridinium Salts of closo-Hydridoborate Anions BnHn 2- (n = 6,10, or 12)",

abstract = "2-(2-Pyridylamino)pyridinium salts (Hpy2NH)2B12H12, (Hpy2NH)2B10H10 - 2H2O, and (Hpy2NH)2B6H6 - 2H2O were synthesized and then characterized by IR spectroscopy. On the basis of IR spectroscopic data, the behavior of imino groups of 2-(2-pyridylamino)pyridinium in the title compounds is considered. X-ray structural analysis of the (Hpy2NH)2B10H10 - 2H2O is performed. The crystals are triclinic, a = 9.649(2) {\AA}, b = 10.020(1) {\AA}, c = 14.924 {\AA}, α = 93.23(2)°, β = 98.44(2)°, γ = 106.45(1)°, V = 1361.6(6) {\AA}3, space group P {\v 1} (no. 2), Z = 2.",

author = "Orlova, {A. M.} and Mustyatsa, {V. N.} and Goeva, {L. V.} and Katser, {S. B.} and Solntsev, {K. A.} and Kuznetsov, {N. T.}",

year = "1996",

language = "English",

volume = "41",

pages = "1856--1861",

journal = "Russian Journal of Inorganic Chemistry",

issn = "0036-0236",

publisher = "Maik Nauka-Interperiodica Publishing",

number = "12",

}

TY - JOUR

T1 - 2-(2-Pyridylamino)pyridinium Salts of closo-Hydridoborate Anions BnHn 2- (n = 6,10, or 12)

AU - Orlova, A. M.

AU - Mustyatsa, V. N.

AU - Goeva, L. V.

AU - Katser, S. B.

AU - Solntsev, K. A.

AU - Kuznetsov, N. T.

PY - 1996

Y1 - 1996

N2 - 2-(2-Pyridylamino)pyridinium salts (Hpy2NH)2B12H12, (Hpy2NH)2B10H10 - 2H2O, and (Hpy2NH)2B6H6 - 2H2O were synthesized and then characterized by IR spectroscopy. On the basis of IR spectroscopic data, the behavior of imino groups of 2-(2-pyridylamino)pyridinium in the title compounds is considered. X-ray structural analysis of the (Hpy2NH)2B10H10 - 2H2O is performed. The crystals are triclinic, a = 9.649(2) Å, b = 10.020(1) Å, c = 14.924 Å, α = 93.23(2)°, β = 98.44(2)°, γ = 106.45(1)°, V = 1361.6(6) Å3, space group P 1̌ (no. 2), Z = 2.

AB - 2-(2-Pyridylamino)pyridinium salts (Hpy2NH)2B12H12, (Hpy2NH)2B10H10 - 2H2O, and (Hpy2NH)2B6H6 - 2H2O were synthesized and then characterized by IR spectroscopy. On the basis of IR spectroscopic data, the behavior of imino groups of 2-(2-pyridylamino)pyridinium in the title compounds is considered. X-ray structural analysis of the (Hpy2NH)2B10H10 - 2H2O is performed. The crystals are triclinic, a = 9.649(2) Å, b = 10.020(1) Å, c = 14.924 Å, α = 93.23(2)°, β = 98.44(2)°, γ = 106.45(1)°, V = 1361.6(6) Å3, space group P 1̌ (no. 2), Z = 2.

UR - http://www.scopus.com/inward/record.url?scp=0010803774&partnerID=8YFLogxK

UR - http://www.scopus.com/inward/citedby.url?scp=0010803774&partnerID=8YFLogxK

M3 - Article

AN - SCOPUS:0010803774

VL - 41

SP - 1856

EP - 1861

JO - Russian Journal of Inorganic Chemistry

JF - Russian Journal of Inorganic Chemistry

SN - 0036-0236

IS - 12

ER -

2-(2-Pyridylamino)pyridinium Salts of closo-Hydridoborate Anions B_nH_n ^2- (n = 6,10, or 12)

Abstract

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