2-(2-Pyridylamino)pyridinium Salts of closo-Hydridoborate Anions BnHn 2- (n = 6,10, or 12)

A. M. Orlova, V. N. Mustyatsa, L. V. Goeva, S. B. Katser, K. A. Solntsev, N. T. Kuznetsov

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5 Citations (Scopus)

Abstract

2-(2-Pyridylamino)pyridinium salts (Hpy2NH)2B12H12, (Hpy2NH)2B10H10 - 2H2O, and (Hpy2NH)2B6H6 - 2H2O were synthesized and then characterized by IR spectroscopy. On the basis of IR spectroscopic data, the behavior of imino groups of 2-(2-pyridylamino)pyridinium in the title compounds is considered. X-ray structural analysis of the (Hpy2NH)2B10H10 - 2H2O is performed. The crystals are triclinic, a = 9.649(2) Å, b = 10.020(1) Å, c = 14.924 Å, α = 93.23(2)°, β = 98.44(2)°, γ = 106.45(1)°, V = 1361.6(6) Å3, space group P 1̌ (no. 2), Z = 2.

Original languageEnglish
Pages (from-to)1856-1861
Number of pages6
JournalRussian Journal of Inorganic Chemistry
Volume41
Issue number12
Publication statusPublished - 1996
Externally publishedYes

ASJC Scopus subject areas

  • Materials Science (miscellaneous)
  • Physical and Theoretical Chemistry
  • Inorganic Chemistry

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